Optical filter and method of manufacturing

ABSTRACT

An optical filter (1a) includes a UV-IR-absorbing layer and has the following characteristics (i) to (v) when light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°: (i) an average transmittance of 78% or more in the wavelength range of 450 nm to 600 nm; (ii) a spectral transmittance of 1% or less in the wavelength range of 750 nm to 1080 nm; (iii) a spectral transmittance of 1% or less in the wavelength range of 300 nm to 350 nm; (iv) a decreasing spectral transmittance with increasing wavelength in the wavelength range of 600 nm to 750 nm and a first IR cut-off wavelength in the wavelength range of 620 nm to 680 nm; and (v) an increasing spectral transmittance with increasing wavelength in the wavelength range of 350 nm to 450 nm and a first UV cut-off wavelength in the wavelength range of 380 nm to 430 nm.

TECHNICAL FIELD

The present invention relates to an optical filter.

BACKGROUND ART

In imaging apparatuses employing an imaging sensor such as a charge coupled device (CCD) or a complementary metal oxide semiconductor (CMOS), any of various optical filters is disposed ahead of the imaging sensor in order to obtain an image with good color reproduction. Imaging sensors generally have spectral sensitivity over a wide wavelength range from the ultraviolet to infrared regions. The visual sensitivity of humans lies solely in the visible region. Thus, a technique is known in which an optical filter shielding against infrared light or ultraviolet light is disposed ahead of an imaging sensor in an imaging apparatus in order to allow the spectral sensitivity of the imaging sensor to approximate to the visual sensitivity of humans.

There are the following types of optical filters: optical filters using light reflection; and optical filters using light absorption. Examples of the former include an optical filter including a dielectric multilayer film, and examples of the latter include an optical filter including a film containing a light absorber capable of absorbing light with a given wavelength. The latter are desirable in view of their spectral properties less likely to vary depending on the incident angle of incident light.

For example, Patent Literature 1 describes a near-infrared-absorbing filter formed of a near-infrared absorber and resin. The near-infrared absorber may include a particular phosphonic acid compound, particular phosphoric acid ester compound, and copper salt. The particular phosphonic acid compound has a monovalent group R¹ bonded to a phosphorus atom P and represented by —CH₂CH₂—R¹¹. Rn represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, or a fluorinated alkyl group having 1 to 20 carbon atoms.

CITATION LIST

-   Literature 1: JP 2011-203467 A

SUMMARY OF INVENTION Technical Problem

Although the near-infrared-absorbing filter described in Patent Literature 1 can effectively absorb light with wavelengths of 800 nm to 1200 nm, it is difficult to say that the near-infrared-absorbing filter described in Patent Literature 1 has desirable light absorption properties in the wavelength range of 350 nm to 400 nm and the wavelength range of 650 nm to 800 nm. Therefore, the present invention provides an optical filter capable of exhibiting, with a simple configuration, desirable optical characteristics that are unachievable by only the near-infrared-absorbing filter described in Patent Literature 1.

Solution to Problem

The present invention provides an optical filter including:

-   -   a UV-IR-absorbing layer capable of absorbing infrared light and         ultraviolet light, wherein     -   when light with wavelengths of 300 nm to 1200 nm is incident at         an incident angle of 0°,     -   (i) the optical filter has an average transmittance of 78% or         more in the wavelength range of 450 nm to 600 nm,     -   (ii) the optical filter has a spectral transmittance of 1% or         less in the wavelength range of 750 nm to 1080 nm,     -   (iii) the optical filter has a spectral transmittance of 1% or         less in the wavelength range of 300 nm to 350 nm,     -   (iv) the optical filter has a decreasing spectral transmittance         with increasing wavelength in the wavelength range of 600 nm to         750 nm and a first IR cut-off wavelength which lies in the         wavelength range of 600 nm to 750 nm and at which the spectral         transmittance is 50% is in the wavelength range of 620 nm to 680         nm, and     -   (v) the optical filter has an increasing spectral transmittance         with increasing wavelength in the wavelength range of 350 nm to         450 nm and a first UV cut-off wavelength which lies in the         wavelength range of 350 nm to 450 nm and at which the spectral         transmittance is 50% is in the wavelength range of 380 nm to 430         nm.

Advantageous Effects of Invention

The above optical filter can exhibit the desirable optical characteristics with a simple configuration.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1A is a cross-sectional view showing an example of an optical filter of the present invention.

FIG. 1B is a cross-sectional view showing another example of the optical filter of the present invention.

FIG. 1C is a cross-sectional view showing yet another example of the optical filter of the present invention.

FIG. 1D is a cross-sectional view showing yet another example of the optical filter of the present invention.

FIG. 1E is a cross-sectional view showing yet another example of the optical filter of the present invention.

FIG. 1F is a cross-sectional view showing yet another example of the optical filter of the present invention.

FIG. 2 is a cross-sectional view showing an example of a camera module including the optical filter of the present invention.

FIG. 3 shows transmittance spectra of an optical filter according to Example 1.

FIG. 4 shows transmittance spectra of an optical filter according to Example 2.

FIG. 5 shows transmittance spectra of an optical filter according to Example 16.

FIG. 6 shows transmittance spectra of an optical filter according to Example 17.

FIG. 7 shows transmittance spectra of an optical filter according to Example 18.

FIG. 8A shows a transmittance spectrum of an infrared-absorbing glass substrate used in Example 21.

FIG. 8B shows a transmittance spectrum of an optical filter according to Example 21. FIG. 9 shows a transmittance spectrum of an optical filter according to Example 22.

FIG. 10 shows a transmittance spectrum of an optical filter according to Example 23.

FIG. 11 shows a transmittance spectrum of an optical filter according to Example 24.

FIG. 12 shows a transmittance spectrum of an optical filter according to Example 38.

DESCRIPTION OF EMBODIMENTS

Hereinafter, embodiments of the present invention will be described with reference to the drawings. The following description is directed to some examples of the present invention, and the present invention is not limited by these examples.

In some cases, it is desirable for optical filters to have properties of permitting transmission of light with wavelengths of 450 nm to 600 nm and cutting off light with wavelengths of 300 nm to 400 nm and wavelengths of 650 nm to 1100 nm. However, for example, the optical filter described in Patent Literature 1 does not have sufficient light absorption properties in the wavelength range of 350 nm to 400 nm and the wavelength range of 650 nm to 800 nm, and a light-absorbing layer or light-reflecting film is additionally needed to cut off light with wavelengths of 350 nm to 400 nm and wavelengths of 650 nm to 800 nm. As just described above, it is difficult to achieve an optical filter having the above desirable properties with a simple structure (for example, a single layer). In fact, the present inventor went through much trial and error to achieve an optical filter having the above desirable properties with a simple structure. That eventually led the present inventor to the optical filter according to the present invention.

As shown in FIG. 1A, the optical filter 1 a includes a UV-IR-absorbing layer 10. The UV-IR-absorbing layer 10 is a layer capable of absorbing infrared light and ultraviolet light. When light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°, the optical filter 1 a exhibits the following optical characteristics (i) to (v).

-   -   (i) An average transmittance of 78% or more in the wavelength         range of 450 nm to 600 nm     -   (ii) A spectral transmittance of 1% or less in the wavelength         range of 750 nm to 1080 nm     -   (iii) A spectral transmittance of 1% or less in the wavelength         range of 300 nm to 350 nm     -   (iv) A decreasing spectral transmittance with increasing         wavelength in the wavelength range of 600 nm to 750 nm and a         first IR cut-off wavelength in the wavelength range of 620 nm to         680 nm     -   (v) An increasing spectral transmittance with increasing         wavelength in the wavelength range of 350 nm to 450 nm and a         first UV cut-off wavelength in the wavelength range of 380 nm to         430 nm

Herein, the term “spectral transmittance” refers to a transmittance obtained when light with a given wavelength is incident on an object such as a specimen, the term “average transmittance” refers to an average of spectral transmittances in a given wavelength range, and the term “maximum transmittance” refers to the maximum spectral transmittance in a given wavelength range. Additionally, the term “transmittance spectrum” herein refers to one in which spectral transmittances at wavelengths in a given wavelength range are arranged in the wavelength order.

Herein, the term “IR cut-off wavelength” refers to a wavelength at which the spectral transmittance is 50% when light with wavelengths of 300 nm to 1200 nm is incident on an optical filter at a given incident angle and which lies in the wavelength range of 600 nm or more. The term “first IR cut-off wavelength” refers to an IR cut-off wavelength for light incident on an optical filter at an incident angle of 0°. Additionally, the term “UV cut-off wavelength” refers to a wavelength at which the spectral transmittance is 50% when light with wavelengths of 300 nm to 1200 nm is incident on an optical filter at a given incident angle and which lies in the wavelength range of 450 nm or less. The term “first UV cut-off wavelength” is a UV cut-off wavelength for light incident on an optical filter at an incident angle of 0°.

As the optical filter 1 a exhibits the above optical characteristics (i) to (v), the optical filter 1 a permits transmission of a large amount of light with wavelengths of 450 nm to 600 nm and can effectively cut off light with wavelengths of 300 nm to 400 nm and wavelengths of 650 nm to 1100 nm. Therefore, a transmittance spectrum of the optical filter 1 a conforms better to the visual sensitivity of humans than does a transmittance spectrum of the near-infrared-absorbing filter described in Patent Literature 1. Moreover, the optical filter 1 a can exhibit the above optical characteristics (i) to (v) without a layer other than the UV-IR-absorbing layer 10.

As to the above (i), the optical filter 1 a desirably has an average transmittance of 80% or more and more desirably an average transmittance of 82% or more in the wavelength range of 450 nm to 600 nm.

As to the above (iii), the optical filter 1 a desirably has a spectral transmittance of 1% or less in the wavelength range of 300 nm to 360 nm. This allows the optical filter 1 a to more effectively cut off light in the ultraviolet region.

As to the above (iv), the first IR cut-off wavelength (a wavelength at which the spectral transmittance is 50%) desirably lies in the wavelength range of 630 nm to 650 nm. In this case, a transmittance spectrum of the optical filter 1 a conforms better to the visual sensitivity of humans.

As to the above (v), the first UV cut-off wavelength (a wavelength at which the spectral transmittance is 50%) desirably lies in the wavelength range of 390 nm to 420 nm. In this case, a transmittance spectrum of the optical filter 1 a conforms better to the visual sensitivity of humans.

The optical filter 1 a desirably exhibits the following optical characteristic (vi) when light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°. The optical filter 1 a can thus shield against infrared light with a relatively long wavelength (a wavelength of 1000 to 1100 nm). Conventionally, a light-reflecting film formed of a dielectric multilayer film is commonly used to cut off light with such a wavelength. The optical filter 1 a can effectively cut off light with such a wavelength without using such a dielectric multilayer film. Even when a light-reflecting film formed of a dielectric multilayer film is necessary, the optical filter 1 a can lower a reflection performance level required of the light-reflecting film. Therefore, the number of dielectrics laminated in the light-reflecting film can be decreased and the cost needed to form the light-reflecting film can be decreased.

-   -   (vi) A spectral transmittance of 3% or less in the wavelength         range of 1000 to 1100 nm

The optical filter 1 a desirably exhibits the following optical characteristic (vii) when light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°. In this case, infrared light with a longer wavelength (1100 to 1200 nm) can be cut off. This allows the optical filter 1 a to effectively cut off light with such a wavelength without using a dielectric multilayer film or with a small number of dielectrics laminated in a dielectric multilayer film.

-   -   (vii) A spectral transmittance of 15% or less in the wavelength         range of 1100 to 1200 nm

For example, in the optical filter 1 a, an absolute value of a difference between a second IR cut-off wavelength and the first IR cut-off wavelength is 10 nm or less (optical characteristic (viii)). The second IR cut-off wavelength is an IR cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 40°. In this case, the transmittance properties of the optical filter 1 a in the vicinity of the first IR cut-off wavelength are less likely to vary with the incident angle of light incident on the optical filter 1 a. Consequently, a central portion and peripheral portion of an image obtained using an imaging apparatus in which the optical filter 1 a is disposed ahead of an imaging sensor can be prevented from presenting unintended color tones.

In the optical filter 1 a, the absolute value of the difference between the second IR cut-off wavelength and first IR cut-off wavelength is desirably 5 nm or less.

For example, in the optical filter 1 a, an absolute value of a difference between a third IR cut-off wavelength and the first IR cut-off wavelength is 15 nm or less (optical characteristic (ix)). The third IR cut-off wavelength is an IR cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 50°. In this case, even when the incident angle of light incident on the optical filter 1 a greatly changes, variation in transmittance properties in the vicinity of the first IR cut-off wavelength of the optical filter 1 a can be reduced. Consequently, high-quality images can be easily obtained when the optical filter 1 a is disposed ahead of an imaging sensor in an imaging apparatus capable of capturing images at a wide angle of view.

For example, in the optical filter 1 a, an absolute value of a difference between a fourth IR cut-off wavelength and the first IR cut-off wavelength is 20 nm or less. The fourth IR cut-off wavelength is an IR cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 60°. In this case, high-quality images can be easily obtained when the optical filter 1 a is disposed ahead of an imaging sensor in an imaging apparatus capable of capturing images at a wide angle of view.

For example, in the optical filter 1 a, an absolute value of a difference between a second UV cut-off wavelength and the first UV cut-off wavelength is 10 nm or less (optical characteristic (x)). The second UV cut-off wavelength is a UV cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 40°. In this case, the transmittance properties of the optical filter 1 a in the vicinity of the first UV cut-off wavelength are less likely to vary with the incident angle of light incident on the optical filter 1 a. Consequently, a central portion and peripheral portion of an image obtained using an imaging apparatus in which the optical filter 1 a is disposed ahead of an imaging sensor can be prevented from presenting unintended color tones.

In the optical filter 1 a, the absolute value of the difference between the second UV cut-off wavelength and first UV cut-off wavelength is desirably 5 nm or less.

For example, in the optical filter 1 a, an absolute value of a difference between a third UV cut-off wavelength and the first UV cut-off wavelength is 15 nm or less (optical characteristic (xi)). The third UV cut-off wavelength is a UV cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 50°. In this case, even when the incident angle of light incident on the optical filter 1 a greatly changes, variation in transmittance properties in the vicinity of the first UV cut-off wavelength of the optical filter 1 a can be reduced. Consequently, high-quality images can be easily obtained when the optical filter 1 a is disposed ahead of an imaging sensor in an imaging apparatus capable of capturing images at a wide angle of view.

For example, in the optical filter 1 a, an absolute value of a difference between a fourth UV cut-off wavelength and the first UV cut-off wavelength is 20 nm or less. The fourth UV cut-off wavelength is a UV cut-off wavelength obtained when light with wavelengths of 300 nm to 1200 nm is incident on the optical filter 1 a at an incident angle of 60°. In this case, high-quality images can be easily obtained when the optical filter 1 a is disposed ahead of an imaging sensor in an imaging apparatus capable of capturing images at a wide angle of view.

The optical filter 1 a desirably exhibits the following optical characteristic (xii) when light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°.

-   -   (xii) A spectral transmittance of 0.5% or less and more         desirably a spectral transmittance of 0.1% or less in the         wavelength range of 800 to 950 nm

The optical filter 1 a desirably further exhibits the following optical characteristic (xiii) when light with wavelengths of 300 nm to 1200 nm is incident at an incident angle of 0°.

-   -   (xiii) A spectral transmittance of 0.5% or less and more         desirably a spectral transmittance of 0.1% or less in the         wavelength range of 800 to 1000 nm

RGB color filters used in imaging apparatuses not only permit transmission of light in wavelength ranges of the corresponding RGB colors but sometimes permit transmission of light with wavelengths of 800 nm or more. Therefore, in the case where an infrared cut filter used in an imaging apparatus has a spectral transmittance not reduced to a certain level in the above wavelength range, light in the above wavelength range is incident on a pixel of an imaging sensor and the corresponding signal is output from the pixel. When the imaging apparatus is used to obtain a digital image under a sufficiently large amount of visible light, the obtained digital image is not greatly affected by a small amount of infrared light transmitted through a color filter and received by a pixel of the imaging sensor. However, such infrared light tends to have a stronger influence under a small amount of visible light or on a dark part of an image, and sometimes a bluish or reddish color is added to the image.

As described above, color filters used along with imaging sensors such as a CMOS and CCD sometimes permit transmission of light in the wavelength range of 800 to 950 nm or 800 to 1000 nm. The optical filter 1 a having the above optical characteristics (xii) and (xiii) can prevent the above defect of images.

The UV-IR-absorbing layer 10 is not particularly limited as long as the UV-IR-absorbing layer 10 absorbs infrared light and ultraviolet light to allow the optical filter 1 a to exhibit the above optical characteristics (i) to (v). The UV-IR-absorbing layer 10, for example, includes a UV-IR absorber formed by a phosphonic acid and copper ion.

When the UV-IR-absorbing layer 10 includes the UV-IR absorber formed by a phosphonic acid and copper ion, the phosphonic acid includes, for example, a first phosphonic acid having an aryl group. In the first phosphonic acid, the aryl group is bonded to a phosphorus atom. Thus, the optical filter 1 a easily exhibits the above optical characteristics (i) to (v).

The aryl group of the first phosphonic acid is, for example, a phenyl group, benzyl group, toluyl group, nitrophenyl group, hydroxyphenyl group, halogenated phenyl group in which at least one hydrogen atom of a phenyl group is substituted by a halogen atom, or halogenated benzyl group in which at least one hydrogen atom of a benzene ring of a benzyl group is substituted by a halogen atom. The first phosphonic acid desirably includes a portion that has the halogenated phenyl group. In that case, the optical filter 1 a easily exhibits the above optical characteristics (i) to (v) more reliably.

When the UV-IR-absorbing layer 10 includes the UV-IR absorber formed by the phosphonic acid and copper ion, the phosphonic acid desirably further includes a second phosphonic acid having an alkyl group. In the second phosphonic acid, the alkyl group is bonded to a phosphorus atom.

The alkyl group of the second phosphonic acid is, for example, an alkyl group having 6 or less carbon atoms. This alkyl group may be linear or branched.

When the UV-IR-absorbing layer 10 includes the UV-IR absorber formed by the phosphonic acid and copper ion, the UV-IR-absorbing layer 10 desirably further includes a phosphoric acid ester allowing the UV-IR absorber to be dispersed and matrix resin.

The phosphoric acid ester included in the UV-IR-absorbing layer 10 is not limited to any particular one, as long as the phosphoric acid ester allows good dispersion of the UV-IR absorber. For example, the phosphoric acid ester includes at least one of a phosphoric acid diester represented by the following formula (c1) and a phosphoric acid monoester represented by the following formula (c2). In the formulae (c1) and (c2), R₂₁, R₂₂, and R₃ are each a monovalent functional group represented by —(CH₂CH₂O)_(n)R₄, wherein n is an integer of 1 to 25 and R₄ is an alkyl group having 6 to 25 carbon atoms. R₂₁, R₂₂, and R₃ may be the same or different functional groups.

The phosphoric acid ester is not particularly limited. The phosphoric acid ester can be, for example, PLYSURF A208N (polyoxyethylene alkyl (C12, C13) ether phosphoric acid ester), PLYSURF A208F (polyoxyethylene alkyl (C8) ether phosphoric acid ester), PLYSURF A208B (polyoxyethylene lauryl ether phosphoric acid ester), PLYSURF A219B (polyoxyethylene lauryl ether phosphoric acid ester), PLYSURF AL (polyoxyethylene styrenated phenylether phosphoric acid ester), PLYSURF A212C (polyoxyethylene tridecyl ether phosphoric acid ester), or PLYSURF A215C (polyoxyethylene tridecyl ether phosphoric acid ester). All of these are products manufactured by DKS Co., Ltd. The phosphoric acid ester can be NIKKOL DDP-2 (polyoxyethylene alkyl ether phosphoric acid ester), NIKKOL DDP-4 (polyoxyethylene alkyl ether phosphoric acid ester), or NIKKOL DDP-6 (polyoxyethylene alkyl ether phosphoric acid ester). All of these are products manufactured by Nikko Chemicals Co., Ltd.

The matrix resin included in the UV-IR-absorbing layer 10 is, for example, a heat-curable or ultraviolet-curable resin in which the UV-IR absorber is dispersible. Additionally, as the matrix resin can be used a resin that has a transmittance of, for example, 70% or more, desirably 75% or more, and more desirably 80% or more for light with wavelengths of 350 nm to 900 nm in the form of a 0.1-mm-thick resin layer. The content of the phosphonic acid is, for example, 3 to 180 parts by mass with respect to 100 parts by mass of the matrix resin.

The matrix resin included in the UV-IR-absorbing layer 10 is not particularly limited as long as the above properties are satisfied. The matrix resin is, for example, a (poly)olefin resin, polyimide resin, polyvinyl butyral resin, polycarbonate resin, polyamide resin, polysulfone resin, polyethersulfone resin, polyamideimide resin, (modified) acrylic resin, epoxy resin, or silicone resin. The matrix resin may contain an aryl group such as a phenyl group and is desirably a silicone resin containing an aryl group such as a phenyl group. If the UV-IR-absorbing layer 10 is excessively hard (rigid), the likelihood of cure shrinkage-induced cracking during the production process of the optical filter 1 a increases with increasing thickness of the UV-IR-absorbing layer 10. When the matrix resin is a silicone resin containing an aryl group, the UV-IR-absorbing layer 10 is likely to have high crack resistance. Moreover, with the use of a silicone resin containing an aryl group, the UV-IR absorber formed by the above phosphonic acid and copper ion is less likely to be aggregated when included. Further, when the matrix resin of the UV-IR-absorbing layer 10 is a silicone resin containing an aryl group, it is desirable for the phosphoric acid ester included in the UV-IR-absorbing layer 10 to have a flexible, linear organic functional group, such as an oxyalkyl group, just as does the phosphoric acid ester represented by the formula (el) or formula (c2). This is because interaction derived from the combination of the above phosphonic acid, a silicone resin containing an aryl group, and phosphoric acid ester having a linear organic functional group such as an oxyalkyl group makes aggregation of the UV-IR absorber less likely and can impart good rigidity and good flexibility to the UV-IR-absorbing layer. Specific examples of the silicone resin available as the matrix resin include KR-255, KR-300, KR-2621-1, KR-211, KR-311, KR-216, KR-212, and KR-251. All of these are silicone resins manufactured by Shin-Etsu Chemical Co., Ltd.

As shown in FIG. 1A, the optical filter 1 a further includes, for example, a transparent dielectric substrate 20, and at least portion of one principal surface of the transparent dielectric substrate 20 is covered with the UV-IR-absorbing layer 10. The transparent dielectric substrate 20 is not limited to any particular one as long as the transparent dielectric substrate 20 is a dielectric substrate having a high average transmittance (e.g., 80% or more) in the wavelength range of 450 nm to 600 nm. In some cases, the transparent dielectric substrate 20 may have the ability to absorb light in the ultraviolet region or infrared region.

The transparent dielectric substrate 20 is, for example, made of glass or resin. When the transparent dielectric substrate 20 is made of glass, the glass is, for example, borosilicate glass such as D 263, soda-lime glass (blue plate glass), white sheet glass such as B 270, alkali-free glass, or infrared-absorbing glass such as copper-containing phosphate glass or copper-containing fluorophosphate glass. When the transparent dielectric substrate 20 is made of infrared-absorbing glass such as copper-containing phosphate glass or copper-containing fluorophosphate glass, the infrared absorption performance necessary for the optical filter 1 a can be achieved by a combination of the infrared absorption performance of the transparent dielectric substrate 20 and the infrared absorption performance of the UV-IR-absorbing layer 10. Therefore, the level of the infrared absorption performance required of the UV-IR-absorbing layer 10 can be lowered. Examples of such an infrared-absorbing glass include BG-60, BG-61, BG-62, BG-63, and BG-67 manufactured by SCHOTT AG, 500EXL manufactured by Nippon Electric Glass Co., Ltd., and CM5000, CM500, C5000, and C500S manufactured by HOYA CORPORATION. Moreover, the infrared-absorbing glass may have ultraviolet absorption properties.

The transparent dielectric substrate 20 may be a transparent crystalline substrate, such as magnesium oxide, sapphire, or quartz. For example, sapphire is very hard and is thus scratch resistant. Therefore, as a scratch-resistant protective material (protective filter), a sheet-shaped sapphire is sometimes disposed ahead of a camera module or lens included in mobile devices such as smartphones and mobile phones. Formation of the UV-IR-absorbing layer 10 on such a sheet-shaped sapphire makes it possible to protect camera modules and lenses and shield against ultraviolet light or infrared light. This eliminates the need to dispose an optical filter having ultraviolet- or infrared-shielding performance around an imaging sensor such as a CCD or CMOS or inside a camera module. Therefore, the formation of the UV-IR-absorbing layer 10 on a sheet-shaped sapphire can contribute to achievement of camera modules reduced in profile.

When the transparent dielectric substrate 20 is made of resin, the resin is, for example, a (poly)olefin resin, polyimide resin, polyvinyl butyral resin, polycarbonate resin, polyamide resin, polysulfone resin, polyethersulfone resin, polyamideimide resin, (modified) acrylic resin, epoxy resin, or silicone resin.

As shown in FIG. 1A, the UV-IR-absorbing layer 10 is, for example, formed as a single layer in the optical filter 1 a. In this case, the optical filter 1 a has a simple structure.

The optical filter 1 a can be produced, for example, by applying a composition (UV-IR-absorbing composition) for forming the UV-IR-absorbing layer 10 to one principal surface of the transparent dielectric substrate 20 to form a film and drying the film. The method for preparing the UV-IR-absorbing composition and the method for producing the optical filter 1 a will be described with an example in which the UV-IR-absorbing layer 10 includes the UV-IR absorber formed by the phosphonic acid and copper ion.

First, an exemplary method for preparing the UV-IR-absorbing composition will now be described. A copper salt such as copper acetate monohydrate is added to a given solvent such as tetrahydrofuran (THF), and the mixture is stirred to give a copper salt solution. To this copper salt solution is then added a phosphoric acid ester compound such as a phosphoric acid diester represented by the formula (c1) or a phosphoric acid monoester represented by the formula (c2), and the mixture is stirred to prepare a solution A. A solution B is also prepared by adding the first phosphonic acid to a given solvent such as THF and stirring the mixture. When a plurality of phosphonic acids are used as the first phosphonic acid, the solution B may be prepared by adding each phosphonic acid to a given solvent such as THF, stirring the mixture, and mixing a plurality of preliminary liquids each prepared to contain a different phosphonic acid. In the preparation of the solution B, an alkoxysilane monomer is desirably added.

The addition of an alkoxysilane monomer to the UV-IR-absorbing composition can prevent particles of the UV-IR absorber from aggregating with each other. This enables the UV-IR absorber to be dispersed well in the UV-IR-absorbing composition even when the content of the phosphoric acid ester is decreased. When the UV-IR-absorbing composition is used to produce the optical filter 1 a, a treatment is performed so that sufficient hydrolysis and polycondensation reactions of the alkoxysilane monomer occur. Owing to the treatment, a siloxane bond (—Si—O—Si—) is formed and the optical filter 1 a has good moisture resistance. The optical filter 1 a additionally has good heat resistance. This is because a siloxane bond is greater in binding energy and chemically more stable than bonds such as a —C—C— bond and —C—O— bond and is thus excellent in heat resistance and moisture resistance.

Next, the solution B is added to the solution A while the solution A is stirred, and the mixture is further stirred for a given period of time. To the resultant solution is then added a given solvent such as toluene, and the mixture is stirred to obtain a solution C. Subsequently, the solution C is subjected to solvent removal under heating for a given period of time to obtain a solution D. This process removes the solvent such as THF and the component such as acetic acid (boiling point: about 118° C.) generated by disassociation of the copper salt and yields a UV-IR absorber formed by the first phosphonic acid and copper ion. The temperature at which the solution C is heated is chosen based on the boiling point of the to-be-removed component disassociated from the copper salt. During the solvent removal, the solvent such as toluene (boiling point: about 110° C.) used to obtain the solution C is also evaporated. A certain amount of this solvent desirably remains in the UV-IR-absorbing composition. This is preferably taken into account in determining the amount of the solvent to be added and the time period of the solvent removal. To obtain the solution C, o-xylene (boiling point: about 144° C.) may be used instead of toluene. In this case, the amount of o-xylene to be added can be reduced to about one-fourth of the amount of toluene to be added, because the boiling point of o-xylene is higher than the boiling point of toluene.

When the UV-IR-absorbing composition further includes the second phosphonic acid, a solution H is additionally prepared for example, as follows. First, a copper salt such as copper acetate monohydrate is added to a given solvent such as tetrahydrofuran (THF), and the mixture is stirred to give a copper salt solution. To this copper salt solution is then added a phosphoric acid ester compound such as a phosphoric acid diester represented by the formula (c1) or a phosphoric acid monoester represented by the formula (c2), and the mixture is stirred to prepare a solution E. A solution F is also prepared by adding the second phosphonic acid to a given solvent such as THF and stirring the mixture. When a plurality of phosphonic acids are used as the second phosphonic acid, the solution F may be prepared by adding each phosphonic acid to a given solvent such as THF, stirring the mixture, and mixing a plurality of preliminary liquids each prepared to contain a different phosphonic acid. The solution F is added to the solution E while the solution E is stirred, and the mixture is further stirred for a given period of time. To the resultant solution is then added a given solvent such as toluene, and the mixture is stirred to obtain a solution G. Subsequently, the solution G is subjected to solvent removal under heating for a given period of time to obtain a solution H. This process removes the solvent such as THF and the component such as acetic acid generated by disassociation of the copper salt and yields another UV-IR absorber formed by the second phosphonic acid and copper ion. The temperature at which the solution G is heated is determined as in the case of the solution C. The solvent for obtaining the solution G is also determined as in the case of the solution C.

The UV-IR-absorbing composition can be prepared by adding the matrix resin such as a silicone resin to the solution D and stirring the mixture. When the UV-IR-absorbing composition includes the UV-IR absorber formed by the second phosphonic acid and copper ion, the UV-IR-absorbing composition can be prepared by adding the matrix resin such as a silicone resin to the solution D, stirring the mixture to obtain a solution I, and further adding the solution H to the solution I and stirring the mixture.

The UV-IR-absorbing composition is applied to one principal surface of the transparent dielectric substrate 20 to form a film. For example, the UV-IR-absorbing composition in a liquid form is applied by spin coating or with a dispenser to one principal surface of the transparent dielectric substrate 20 to form a film. Next, this film is subjected to a given heat treatment to cure the film. For example, the film is exposed to an environment at a temperature of 50° C. to 200° C. The film is subjected to a humidification treatment, if necessary, to sufficiently hydrolyze the alkoxysilane monomer included in the UV-IR-absorbing composition. For example, the cured film is exposed to an environment at a temperature of 40° C. to 100° C. and a relative humidity of 40% to 100%. A repeating structure (Si—O)_(n)— of a siloxane bond is thus formed. The optical filter 1 a can be produced in this manner. In common hydrolysis and polycondensation reactions of an alkoxysilane containing a monomer, both the alkoxysilane and water are in a liquid composition sometimes. However, if water is added beforehand to the UV-IR-absorbing composition to produce the optical filter, the phosphoric acid ester or UV-IR absorber is deteriorated in the course of the formation of the UV-IR-absorbing layer, and the UV-IR absorption performance can be decreased or the durability of the optical filter can be impaired. Therefore, the humidification treatment is desirably performed after the film is cured by the given heat treatment.

When the transparent dielectric substrate 20 is a glass substrate, a resin layer including a silane coupling agent may be formed between the transparent dielectric substrate 20 and UV-IR-absorbing layer 10 to improve the adhesion between the transparent dielectric substrate 20 and UV-IR-absorbing layer 10.

<Modifications>

The optical filter 1 a can be modified in various respects. For example, the optical filter 1 a may be modified to optical filters 1 b to 1 f shown in FIG. 1B to FIG. 1F. The optical filters 1 b to 1 f are configured in the same manner as the optical filter 1 a, unless otherwise described. The components of the optical filters 1 b to 1 f that are the same as or correspond to those of the optical filter 1 a are denoted by the same reference characters, and detailed descriptions of such components are omitted. The description given for the optical filter 1 a can apply to the optical filters 1 b to 1 f, unless there is technical inconsistency.

As shown in FIG. 1B, the optical filter 1 b according to another example of the present invention has the UV-IR-absorbing layers 10 formed on both principal surfaces of the transparent dielectric substrate 20. Therefore, the optical filter 1 b can exhibit the optical characteristics (i) to (v) owing to the two UV-IR-absorbing layers 10 rather than one UV-IR-absorbing layer 10. The UV-IR-absorbing layers on both principal surfaces of the transparent dielectric substrate 20 may have the same or different thicknesses. That is, the formation of the UV-IR-absorbing layers 10 on both principal surfaces of the transparent dielectric substrate 20 is done so that the two UV-IR-absorbing layers 10 account for equal or unequal proportions of the UV-IR-absorbing layer thickness required for the optical filter 1 b to have desired optical properties. Thus, the thicknesses of the UV-IR-absorbing layers 10 formed on both principal surfaces of the transparent dielectric substrate are relatively small. Thus, the internal pressure of the film is low and occurrence of a crack can be prevented. Additionally, it is possible to shorten the time spent on the application of the UV-IR-absorbing composition in a liquid form and shorten the time taken for the curing of the film of the UV-IR-absorbing composition applied. If the UV-IR-absorbing layer 10 is formed only on one principal surface of the transparent dielectric substrate 20 that is thin, the optical filter may be warped due to a stress induced by shrinkage occurring during formation of the UV-IR-absorbing layer 10 from the UV-IR-absorbing composition. The formation of the UV-IR-absorbing layers 10 on both principal surfaces of the transparent dielectric substrate 20 can reduce warping of the optical filter 1 b even when the transparent dielectric substrate 20 is thin. In this case as well, a resin layer including a silane coupling agent may be formed between the transparent dielectric substrate 20 and UV-IR-absorbing layer 10 to improve the adhesion between the transparent dielectric substrate 20 and UV-IR-absorbing layer 10.

As shown in FIG. 1C, the optical filter 1 c according to another example of the present invention includes an anti-reflection film 30. The anti-reflection film is a film formed as an interface between the optical filter 1 c and air and reducing reflection of visible light. The anti-reflection film 30 is, for example, a film formed of a dielectric made of, for example, a resin, an oxide, or a fluoride. The anti-reflection film 30 may be a multilayer film formed by laminating two or more types of dielectrics having different refractive indices. In particular, the anti-reflection film 30 may be a dielectric multilayer film made of a low-refractive-index material such as SiO₂ and a high-refractive-index material such as TiO₂ or Ta₂O₅. In this case, Fresnel reflection at the interface between the optical filter 1 c and air is reduced and the amount of visible light passing through the optical filter 1 c can be increased. In this case as well, a resin layer including a silane coupling agent may be formed between the transparent dielectric substrate and UV-IR-absorbing layer 10 to improve the adhesion between the transparent dielectric substrate 20 and UV-IR-absorbing layer 10. In some cases, a resin layer including a silane coupling agent may be formed between the UV-IR-absorbing layer 10 and anti-reflection film 30 to improve the adhesion to the anti-reflection film 30. The anti-reflection film 30 may be disposed on each principal surface of the optical filter 1 c, or may be disposed on one principal surface thereof.

As shown in FIG. 1D, the optical filter 1 d according to another example of the present invention consists only of the UV-IR-absorbing layer 10. The optical filter 1 d can be produced, for example, by applying the UV-IR-absorbing composition onto a given substrate such as a glass substrate, resin substrate, or metal substrate (such as a steel substrate or stainless steel substrate) to form a film, curing the film, and then separating the film from the substrate. The optical filter 1 d may be produced by a melt molding method. Not including the transparent dielectric substrate 20, the optical filter 1 d is thin. The optical filter 1 d can thus contribute to achievement of imaging sensors and optical systems reduced in profile.

As shown in FIG. 1E, the optical filter 1 e according to another example of the present invention includes the UV-IR-absorbing layer 10 and a pair of the anti-reflection films 30 disposed on both sides of the UV-IR-absorbing layer 10. In this case, the optical filter 1 e can contribute to achievement of imaging sensors and optical systems reduced in profile, and can increase the amount of visible light passing therethrough more than the optical filter 1 d can.

As shown in FIG. 1F, the optical filter if according to another example of the present invention includes the UV-IR-absorbing layer 10 and a reflecting film 40 disposed on one principal surface of the UV-IR-absorbing layer 10 and capable of reflecting infrared light and/or ultraviolet light. The reflecting film 40 is, for example, a film formed by vapor deposition of a metal such as aluminum or a dielectric multilayer film in which a layer formed of a high-refractive-index material and a layer formed of a low-refractive-index material are alternately laminated. A material, such as TiO₂, ZrO₂, Ta₂O₅, Nb₂O₅, ZnO, or In₂O₃, having a refractive index of 1.7 to 2.5 is used as the high-refractive-index material. A material, such as SiO₂, Al₂O₃, or MgF₂, having a refractive index of 1.2 to 1.6 is used as the low-refractive-index material. Examples of the method for forming the dielectric multilayer film include chemical vapor deposition (CVD), sputtering, and vacuum deposition. The reflecting film may be formed as each principal surface of the optical filter (not shown). The reflecting films formed on both principal surfaces of the optical filter balance the stress on the front side and that on the back side, and that offers an advantage of decreasing the likelihood of warping of the optical filter.

The optical filters 1 a to if may be modified to include an infrared-absorbing film (not shown) in addition to the UV-IR-absorbing layer 10, if necessary. The infrared-absorbing film includes, for example, an organic infrared absorber, such as a cyanine-based, phthalocyanine-based, squarylium-based, diimmonium-based, or azo-based infrared absorber or an infrared absorber composed of a metal complex. The infrared-absorbing film includes, for example, one infrared absorber or two or more infrared absorbers selected from these infrared absorbers. The organic infrared absorber can absorb light in a relatively narrow wavelength range (absorption band) and is suitable for absorbing light with a wavelength in a given range.

The optical filters 1 a to if may be modified to include an ultraviolet-absorbing film (not shown) in addition to the UV-IR-absorbing layer 10, if necessary. The ultraviolet-absorbing film includes, for example, an ultraviolet absorber, such as a benzophenone-based, triazine-based, indole-based, merocyanine-based, or oxazole-based ultraviolet absorber. The ultraviolet-absorbing film, for example, includes one ultraviolet absorber or two or more ultraviolet absorbers selected from these ultraviolet absorbers. The ultraviolet absorber can include ultraviolet absorbers absorbing ultraviolet light with a wavelength, for example, around 300 nm to 340 nm, emitting light (fluorescence) with a wavelength longer than the absorbed wavelength, and functioning as a fluorescent agent or fluorescent brightener. The ultraviolet-absorbing film can reduce incidence of ultraviolet light which deteriorates the materials, such as resin, used in the optical filter.

The above infrared absorber or ultraviolet absorber may be contained beforehand in the transparent dielectric substrate 20 made of the resin. The infrared-absorbing film and ultraviolet-absorbing film each can be formed, for example, by forming a resin containing the infrared absorber or ultraviolet absorber into a film. In this case, it is necessary for the resin to allow the infrared absorber or ultraviolet absorber to be appropriately dissolved or dispersed therein and be transparent. Examples of such a resin include a (poly)olefin resin, polyimide resin, polyvinyl butyral resin, polycarbonate resin, polyamide resin, polysulfone resin, polyethersulfone resin, polyamideimide resin, (modified) acrylic resin, epoxy resin, and silicone resin.

The optical filters 1 a to if may be modified to further include a reflecting film reflecting infrared light and/or ultraviolet light, if necessary. As such a reflecting film can be used, for example, a film formed by vapor deposition of a metal such as aluminum or a dielectric multilayer film in which a layer formed of a high-refractive-index material and a layer formed of a low-refractive-index material are alternately laminated. The reflecting film may be formed as each principal surface of the optical filter, or may be formed as one principal surface of the optical filter. When the reflecting film is formed in the former manner, the stress on the front side and that on the back side are balanced, and that decreases the likelihood of warping of the optical filter. When the reflecting film is a dielectric multilayer film, a material, such as TiO₂, ZrO₂, Ta₂O₅, Nb₂O₅, ZnO, or In₂O₃, having a refractive index of 1.7 to 2.5 is used as the high-refractive-index material. A material, such as SiO₂, Al₂O₃, or MgF₂, having a refractive index of 1.2 to 1.6 is used as the low-refractive-index material. Examples of the method for forming the dielectric multilayer film include chemical vapor deposition (CVD), sputtering, and vacuum deposition.

The optical filters 1 a to if are each disposed ahead (on the side closer to an object) of an imaging sensor, such as a CCD or CMOS, in an imaging apparatus in order to, for example, allow the spectral sensitivity of the imaging sensor in the imaging apparatus to approximate to the visual sensitivity of humans.

Further, as shown in FIG. 2 , a camera module 100 employing, for example, the optical filter 1 a can be provided. The camera module 100 includes, for example, a lens system 2, a low-pass filter 3, an imaging sensor 4, a circuit board 5, an optical filter support housing 7, and an optical system housing 8 in addition to the optical filter 1 a. The rim of the optical filter 1 a is, for example, fitted to a ring-shaped recessed portion adjacent to an opening formed in the middle of the optical filter support housing 7. The optical filter support housing 7 is fixed to the optical system housing 8. In the optical system housing 8, the lens system 2, low-pass filter 3, and imaging sensor 4 are disposed in this order along an optical axis. The imaging sensor 4 is, for example, a CCD or CMOS. After the ultraviolet and infrared portions of light coming from an object are cut by the optical filter 1 a, the resultant light is focused by the lens system 2 and then goes through the low-pass filter 3 to enter the imaging sensor 4. An electrical signal generated by the imaging sensor 4 is sent outside the camera module 100 by the circuit board 5.

In the camera module 100, the optical filter 1 a functions also as a cover (protective filter) that protects the lens system 2. In this case, a sapphire substrate is desirably used as the transparent dielectric substrate 20 of the optical filter 1 a. Having high scratch-resistance, a sapphire substrate is desirably disposed, for example, on the external side (the side opposite to the imaging sensor 4). The optical filter 1 a consequently exhibits high scratch-resistance, for example, on external contact and has the optical characteristics (i) to (v) (and desirably further has the optical characteristics (vi) to (xiii)). This eliminates the need to dispose an optical filter for cutting off infrared light or ultraviolet light near the imaging sensor 4 and facilitates a reduction of the camera module 100 in profile. It should be noted that FIG. 2 showing the camera module 100 is a schematic diagram illustrating an example of, for example, the disposition of the parts, and describes an embodiment where the optical filter 1 a is used as a protective filter. As long as the optical filter 1 a functions as a protective filter, the camera module employing the optical filter 1 a is not limited to the one shown in FIG. 2 . If necessary, the low-pass filter 3 may be omitted or another filter may be included.

EXAMPLES

The present invention will be described in more detail by examples. The present invention is not limited to the examples given below. First, methods for evaluation of optical filters according to Examples and Comparative Examples will be described.

<Measurement of Transmittance Spectra of Optical Filter>

Transmittance spectra shown upon incidence of light with wavelengths of 300 nm to 1200 nm on the optical filters according to Examples and Comparative Examples were measured using an ultraviolet-visible spectrophotometer (manufactured by JASCO Corporation, product name: V-670). The incident angle of the light incident on the optical filters was changed from 0° to 65° at 5° intervals to measure a transmittance spectrum at each angle.

<Measurement of Thickness of UV-IR-Absorbing Layer>

The thicknesses of the optical filters according to Examples and Comparative Examples were measured with a digital micrometer. For each optical filter according to Example or Comparative Example having a transparent dielectric substrate made of, for example, glass, the thickness of the UV-IR-absorbing layer of the optical film was determined by subtracting the thickness of the transparent glass substrate from the thickness of the optical filter measured with a digital micrometer.

Example 1

1.125 g of copper acetate monohydrate ((CH₃COO)₂Cu·H₂O) and 60 g of tetrahydrofuran (THF) were mixed, and the mixture was stirred for 3 hours to obtain a copper acetate solution. To the obtained copper acetate solution was then added 0.412 g of PLYSURF A208N (manufactured by DKS Co., Ltd.) which is a phosphoric acid ester compound, and the mixture was stirred for 30 minutes to obtain a solution A. 10 g of THF was added to 0.441 g of phenylphosphonic acid (C₆H₅PO(OH)₂) (manufactured by Nissan Chemical Industries, Ltd.), and the mixture was stirred for 30 minutes to obtain a solution B-1. 10 g of THF was added to 0.661 g of 4-bromophenylphosphonic acid (C₆H₄BrPO(OH)₂) (manufactured by Tokyo Chemical Industry Co., Ltd.), and the mixture was stirred for 30 minutes to obtain a solution B-2. Next, the solutions B-1 and B-2 were mixed, and the mixture was stirred for 1 minute. 1.934 g of methyltriethoxysilane (MTES: CH₃Si(OC₂H₅)₃) (manufactured by Shin-Etsu Chemical Co., Ltd.) and 0.634 g of tetraethoxysilane (TEOS: Si(OC₂H₅)₄) (manufactured by KISHIDA CHEMICAL Co., Ltd., special grade) were added, and the mixture was further stirred for 1 minute to obtain a solution B. The solution B was added to the solution A while the solution A was stirred, and the mixture was stirred at room temperature for 1 minute. To the resultant solution was then added 25 g of toluene, and the mixture was stirred at room temperature for 1 minute to obtain a solution C. This solution C was placed in a flask and subjected to solvent removal using a rotary evaporator (manufactured by Tokyo Rikakikai Co., Ltd., product code: N-1110SF) under heating by means of an oil bath (manufactured by Tokyo Rikakikai Co., Ltd., product code: OSB-2100). The temperature of the oil bath was controlled to 105° C.

A solution D which had been subjected to the solvent removal was then collected from the flask. The solution D which is a dispersion of fine particles of copper phenyl-based phosphonate (absorber) including copper phenylphosphonate and copper 4-bromophenylphosphonate was transparent, and the fine particles were well dispersed therein.

0.225 g of copper acetate monohydrate and 36 g of THF were mixed, and the mixture was stirred for 3 hours to obtain a copper acetate solution. To the obtained copper acetate solution was then added 0.129 g of PLYSURF A208N which is a phosphoric acid ester compound, and the mixture was stirred for 30 minutes to obtain a solution E. 10 g of THF was added to 0.144 g of n-butylphosphonic acid (C₄H₉PO(OH)₂) (manufactured by Nippon Chemical Industrial Co., Ltd.), and the mixture was stirred for 30 minutes to obtain a solution F. The solution F was added to the solution E while the solution E was stirred, and the mixture was stirred at room temperature for 1 minute. To the resultant solution was then added 25 g of toluene, and the mixture was stirred at room temperature for 1 minute to obtain a solution G. This solution G was placed in a flask and subjected to solvent removal using a rotary evaporator under heating by means of an oil bath. The temperature of the oil bath was controlled to 105° C. A solution H which had been subjected to the solvent removal was then collected from the flask. The solution H which is a dispersion of fine particles of copper butylphosphonate was transparent, and the fine particles were well dispersed therein.

To the solution D was added 2.200 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a solution I. The solution H was added to the solution I, and the mixture was stirred for 30 minutes to obtain a UV-IR-absorbing composition (solution J) according to Example 1. For the UV-IR-absorbing composition (solution J) according to Example 1, the contents of the components are shown in Table 1 on a mass basis, and the contents of the components and the percentage contents of the phosphonic acids are shown in Table 2 on an amount-of-substance basis. The percentage content of each phosphonic acid is determined by rounding a value to one decimal place, and thus the sum of the percentage contents may not always be 100 mol %.

The UV-IR-absorbing composition according to Example 1 was applied with a dispenser to a 30 mm×30 mm central region of one principal surface of a transparent glass substrate (manufactured by SCHOTT AG, product name: D 263) made of borosilicate glass and having dimensions of 76 mm×76 mm×0.21 mm. A film was thus formed on the substrate. The thickness of the film was determined through trial and error so that the optical filter would have an average transmittance of about 1% in the wavelength range of 700 to 730 nm. When the UV-IR-absorbing composition was applied to the transparent glass substrate, a frame having an opening corresponding in dimensions to the region where the film-forming liquid was applied was put on the transparent glass substrate to hold back the film-forming liquid and prevent the film-forming liquid from spreading. The amount of the film-forming liquid applied was adjusted, so that the film obtained had a desired thickness. Subsequently, the transparent glass substrate with the undried film was placed in an oven and heat-treated at 85° C. for 6 hours to cure the film. After that, the transparent glass substrate with the film formed thereon was placed in a thermo-hygrostat set at a temperature of 85° C. and a relative humidity of 85% for a 20-hour humidification treatment. An optical filter according to Example 1 including a UV-IR-absorbing layer formed on a transparent glass substrate was thus obtained. The humidification treatment was performed to promote hydrolysis and polycondensation of the alkoxysilanes contained in the UV-IR-absorbing composition applied onto the transparent glass substrate and form a hard and dense matrix of the UV-IR-absorbing layer. The thickness of the UV-IR-absorbing layer of the optical filter according to Example 1 was 170 μm. Transmittance spectra shown by the optical filter according to Example 1 at incident angles ranging from 0° to 65° were measured. The transmittance spectra shown thereby at incident angles of 0°, 40°, 50°, and 60° are shown in FIG. 3 . The results of observing the transmittance spectrum shown by the optical filter according to Example 1 at an incident angle of 0° are shown in Tables 7 and 8. “Wavelength range in which transmittance is 78% or more” in Table 8 refers to a wavelength range which is in the wavelength range of 400 nm to 600 nm and in which the spectral transmittance is 78% or more. “Wavelength range in which transmittance is 1% or less” as to the infrared region properties in Table 8 refers to a wavelength range which is in the wavelength range of 700 nm to 1200 nm and in which the spectral transmittance is 1% or less. “Wavelength range in which transmittance is 0.1% or less” as to the infrared region properties in Table 8 refers to a wavelength range which is in the wavelength range of 700 nm to 1200 nm and in which the spectral transmittance is 0.1% or less. “Wavelength range in which transmittance is 1% or less” as to the ultraviolet region properties in Table 8 refers to a wavelength range which is in the wavelength range of 300 nm to 400 nm and in which the spectral transmittance is 1% or less. “Wavelength range in which transmittance is 0.1% or less” as to the ultraviolet region properties in Table 8 refers to a wavelength range which is in the wavelength range of 300 nm to 400 nm and in which the spectral transmittance is 0.1% or less. The same can be said in Tables 10, 12, 14, 16, 18, and 20. Moreover, the results (incident angles: 0° to 65°) of observing the transmittance spectra shown by the optical filter according to Example 1 at incident angles of 0° and 30° to 65° (at 5° intervals) are shown in Tables 11 and 12.

Examples 2 to 15

UV-IR-absorbing compositions according to Examples 2 to 15 were prepared in the same manner as in Example 1, except that the amounts of the compounds added were adjusted as shown in Table 1. Optical filters according to Examples 2 to 15 were produced in the same manner as in Example 1, except that the UV-IR-absorbing compositions according to Examples 2 to 15 were used instead of the UV-IR-absorbing composition according to Example 1 and that the thicknesses of the UV-IR-absorbing layers were adjusted as shown in Table 1. The contents and percentage contents of the phosphonic acids are shown in Table 2 on an amount-of-substance basis. The percentage content of each phosphonic acid is determined by rounding a value to one decimal place, and thus the sum of the percentage contents may not always be 100 mol %. Transmittance spectra shown by the optical filter according to Example 2 at incident angles ranging from 0° to 65° were measured. The transmittance spectra shown thereby at incident angles of 0°, 40°, 50°, and 60° are shown in FIG. 4 . The results of observing the transmittance spectrum shown by the optical filter according to Example 2 at an incident angle of are shown in Tables 7 and 8. Moreover, the results of observing the transmittance spectra shown by the optical filter according to Example 2 at incident angles of 0° and 30° to 65° (at 5° intervals) are shown in Tables 13 and 14. Additionally, the results of observing the transmittance spectra shown by the optical filters according to Examples 3 to 15 at an incident angle of 0° are shown in Tables 7 and 8.

Example 16

The UV-IR-absorbing composition according to Example 2 was applied with a dispenser to a 30 mm×30 mm central region of one principal surface of a transparent glass substrate (manufactured by SCHOTT AG, product name: D 263) made of borosilicate glass and having dimensions of 76 mm×76 mm×0.21 mm. A film having a given thickness was thus formed on the substrate. When the UV-IR-absorbing composition was applied to the transparent glass substrate, a frame having an opening corresponding in dimensions to the region where the film-forming liquid was applied was put on the transparent glass substrate to hold back the film-forming liquid and prevent the film-forming liquid from spreading. Next, the transparent glass substrate with the undried film was placed in an oven and heat-treated at 85° C. for 6 hours to cure the film. After that, the film was separated from the transparent glass substrate. The separated film was placed in a thermo-hygrostat set at a temperature of 85° C. and a relative humidity of 85% for a 20-hour humidification treatment. An optical filter according to Example 16 consisting only of a UV-IR-absorbing layer was thus obtained. The thickness of the light-absorbing layer alone was measured with a digital micrometer. The thickness of the optical filter according to Example 16 turned out to be 132 μm. Transmittance spectra shown by the optical filter according to Example 16 at incident angles ranging from 0° to 65° were measured. The transmittance spectra shown thereby at incident angles of 0°, 40°, 50°, and 60° are shown in FIG. 5 . The results of observing the transmittance spectrum shown by the optical filter according to Example 16 at an incident angle of 0° are shown in Tables 7 and 8. Moreover, the results of observing the transmittance spectra shown by the optical filter according to Example 16 at incident angles of 0° and 30° to 65° (at 5° intervals) are shown in Tables 15 and 16.

Example 17

The UV-IR-absorbing composition according to Example 2 was applied with a dispenser to a 30 mm×30 mm central region of one principal surface of a transparent glass substrate (manufactured by SCHOTT AG, product name: D 263) made of borosilicate glass and having dimensions of 76 mm×76 mm×0.21 mm. A film with about half the thickness of the film in Example 2 was thus formed on the substrate. When the UV-IR-absorbing composition was applied to the transparent glass substrate, a frame having an opening corresponding in dimensions to the region where the film-forming liquid was applied was put on the transparent glass substrate to hold back the film-forming liquid and prevent the film-forming liquid from spreading. Next, the transparent glass substrate with the undried film was placed in an oven and heat-treated at 85° C. for 6 hours to cure the film. Subsequently, the UV-IR-absorbing composition according to Example 2 was applied with a dispenser to a 30 mm×30 mm central region of the other principal surface of the transparent glass substrate. A film with about half the thickness of the thickness of the film in Example 2 was thus formed on the substrate. When the UV-IR-absorbing composition was applied to the transparent glass substrate, a frame having an opening corresponding in dimensions to the region where the film-forming liquid was applied was put on the transparent glass substrate to hold back the film-forming liquid and prevent the film-forming liquid from spreading. Next, the transparent glass substrate with the undried film was placed in an oven and heat-treated at 85° C. for 6 hours to cure the film. Then, the transparent glass substrate with the above films formed on both principal surfaces thereof was placed in a thermo-hygrostat set at a temperature of 85° C. and a relative humidity of 85% for a 20-hour humidification treatment. An optical filter according to Example 17 in which UV-IR-absorbing layers were formed on both sides of a transparent glass substrate was thus obtained. The sum of the thicknesses of the UV-IR-absorbing layers formed on both sides of the transparent glass substrate was 193 μm. Transmittance spectra shown by the optical filter according to Example 17 at incident angles ranging from 0° to 65° were measured. The transmittance spectra shown thereby at incident angles of 0°, 40°, 50°, and 60° are shown in FIG. 6 . The results of observing the transmittance spectrum shown by the optical filter according to Example 17 at an incident angle of 0° are shown in Tables 7 and 8. Moreover, the results of observing the transmittance spectra shown by the optical filter according to Example 17 at incident angles of 0° and 30° to 65° (at 5° intervals) are shown in Tables 17 and 18.

Example 18

An optical filter according to Example 18 in which UV-IR-absorbing layers were formed on both sides of a transparent glass substrate was produced in the same manner as in Example 17, except that a transparent glass substrate (manufactured by SCHOTT AG, product name: D 263) made of borosilicate glass and having dimensions of 76 mm×76 mm×0.07 mm was used instead of the transparent glass substrate as used in Example 17. The sum of the thicknesses of the UV-IR-absorbing layers formed on both sides of the transparent glass substrate was 183 μm. Transmittance spectra shown by the optical filter according to Example 18 at incident angles ranging from 0° to 65° were measured. The transmittance spectra shown thereby at incident angles of 0°, 40°, 50°, and 60° are shown in FIG. 7 . The results of observing the transmittance spectrum shown by the optical filter according to Example 18 at an incident angle of 0° are shown in Tables 7 and 8. The results of observing the transmittance spectra shown by the optical filter according to Example 18 at incident angles of 0° and 30° to 65° (at 5° intervals) are shown in Tables 19 and 20.

Example 19

A UV-IR-absorbing composition according to Example 19 was prepared in the same manner as in Example 1, except that PLYSURF A208F (manufactured by DKS Co., Ltd.) was used as a phosphoric acid ester compound instead of PLYSURF A208N and that the amounts of the compounds added were adjusted as shown in Table 1. An optical filter according to Example 19 was produced in the same manner as in Example 1, except that the UV-IR-absorbing composition according to Example 19 was used instead of the UV-IR-absorbing composition according to Example 1 and that the thickness of the UV-IR-absorbing layer was adjusted to 198 μm. Transmittance spectra shown by the optical filter according to Example 19 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 7 and 8.

Example 20

A UV-IR-absorbing composition according to Example 20 was prepared in the same manner as in Example 1, except that 4-fluorophenylphosphonic acid (C₆H₄FPO(OH)₂) (manufactured by Tokyo Chemical Industry Co., Ltd.) was used instead of 4-bromophenylphosphonic acid and that the amounts of the compounds added were adjusted as shown in Table 1. An optical filter according to Example was produced in the same manner as in Example 1, except that the UV-IR-absorbing composition according to Example 20 was used instead of the UV-IR-absorbing composition according to Example 1 and that the thickness of the UV-IR-absorbing layer was adjusted to 168 μm. Transmittance spectra shown by the optical filter according to Example 20 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 7 and 8.

Example 21

An optical filter according to Example 21 was produced in the same manner as in Example 2, except that a 100-μm-thick infrared-absorbing glass substrate was used instead of the transparent glass substrate as used in Example 2 and that the thickness of the UV-IR-absorbing layer was adjusted to 76 μm. This infrared-absorbing glass substrate contains copper and has a transmittance spectrum shown in FIG. 8A. A transmittance spectrum shown by the optical filter according to Example 21 at an incident angle of 0° was measured. The result is shown in FIG. 8B. Moreover, the results of observing the transmittance spectrum shown by the optical filter according to Example 21 at an incident angle of 0° are shown in Tables 7 and 8.

Examples 22 to 37

Optical filters according to Examples 22 to 37 were each produced in the same manner as in Example 2, except that the conditions of the humidification treatment of the dried film were changed as shown in Table 3 and that the thickness of the UV-IR-absorbing layer was adjusted as shown in Table 3. Transmittance spectra shown by the optical filters according to Examples 22 to 24 at an incident angle of 0° were measured. The results are separately shown in FIG. 9 to FIG. 11 . Moreover, the results of observing the transmittance spectra shown by the optical filters according to Examples 22 to 24 at an incident angle of 0° are shown in Tables 7 and 8. Transmittance spectra shown by the optical filters according to Examples 25 to 37 were measured, and the results of observing the transmittance spectra shown thereby at an incident angle of 0° are shown in Tables 7 and 8.

Example 38

An optical filter according to Example 38 was produced in the same manner as in Example 2, except that a 0.3-mm-thick sapphire substrate was used instead of the transparent glass substrate as used in Example 2 and that the thickness of the UV-IR-absorbing layer was adjusted to 168 μm. A transmittance spectrum shown by the optical filter according to Example 38 at an incident angle of 0° was measured. The result is shown in FIG. 12 . The results of observing the transmittance spectrum shown by the optical filter according to Example 38 at an incident angle of 0° are shown in Tables 7 and 8.

Comparative Example 1

A solution D (dispersion of fine particles of copper phenyl-based phosphonate) according to Comparative Example 1 was prepared in the same manner as in Example 1, except that the amounts of the compounds added were adjusted as shown in Tables 4 and 5. To the solution D according to Comparative Example 1 was added 2.200 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a UV-IR-absorbing composition according to Comparative Example 1. An optical filter according to Comparative Example 1 was produced in the same manner as in Example 1, except that the UV-IR-absorbing composition according to Comparative Example 1 was used instead of the UV-IR-absorbing composition according to Example 1 and that the thickness of the UV-IR-absorbing layer was adjusted to 126 μm. Transmittance spectra shown by the optical filter according to Comparative Example 1 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Moreover, based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 1 at an incident angle of 0°, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 1 was changed to 200 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 1.

Comparative Example 2

A solution D (dispersion of fine particles of copper phenyl-based phosphonate) according to Comparative Example 2 was prepared in the same manner as in Example 1, except that the amounts of the compounds added were adjusted as shown in Tables 4 and 5. To the solution D according to Comparative Example 2 was added 4.400 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a UV-IR-absorbing composition according to Comparative Example 2. An optical filter according to Comparative Example 2 was produced in the same manner as in Example 1, except that the UV-IR-absorbing composition according to Comparative Example 2 was used instead of the UV-IR-absorbing composition according to Example 1, that the thickness of the UV-IR-absorbing layer was adjusted to 217 μm, and that the conditions of the heat treatment for curing the film and conditions of the humidification treatment were changed as shown in Table 6. Transmittance spectra shown by the optical filter according to Comparative Example 2 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Moreover, based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 2 at an incident angle of 0°, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 2 was changed to 347 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 2.

Comparative Example 3

1.125 g of copper acetate monohydrate and 60 g of THF were mixed, and the mixture was stirred for 3 hours to obtain a copper acetate solution. To the obtained copper acetate solution was then added 0.624 g of PLYSURF A208F (manufactured by DKS Co., Ltd.), and the mixture was stirred for 30 minutes to obtain a solution A. 10 g of THF was added to 0.832 g of phenylphosphonic acid (manufactured by Nissan Chemical Industries, Ltd.), and the mixture was stirred for 30 minutes to obtain a solution B-1. 1.274 g of MTES (manufactured by Shin-Etsu Chemical Co., Ltd.) and 1.012 g of TEOS (manufactured by KISHIDA CHEMICAL Co., Ltd., special grade) were added to the solution B-1, and the mixture was further stirred for 1 minute to obtain a solution B. The solution B was added to the solution A while the solution A was stirred, and the mixture was stirred at room temperature for 1 minute. To the resultant solution was then added 25 g of toluene, and the mixture was stirred at room temperature for 1 minute to obtain a solution C. This solution C was placed in a flask and subjected to solvent removal using a rotary evaporator (manufactured by Tokyo Rikakikai Co., Ltd., product code: N-1110SF) under heating by means of an oil bath (manufactured by Tokyo Rikakikai Co., Ltd., product code: OSB-2100). The temperature of the oil bath was controlled to 105° C. A solution D according to Comparative Example 3 which had been subjected to the solvent removal was then collected from the flask. The solution D (dispersion of fine particles of copper phenylphosphonate) according to Comparative Example 3 was transparent, and the fine particles were well dispersed therein.

To the solution D according to Comparative Example 3 was added 4.400 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a UV-IR-absorbing composition according to Comparative Example 3. An optical filter according to Comparative Example 3 was produced in the same manner as in Example 1, except that the UV-IR-absorbing composition according to Comparative Example 3 was used instead of the UV-IR-absorbing composition according to Example 1, that the thickness of the UV-IR-absorbing layer was adjusted to 198 μm, and that the conditions of the heat treatment for curing the film were changed as shown in Table 6. Transmittance spectra shown by the optical filter according to Comparative Example 3 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Moreover, based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 3, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 3 was changed to 303 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 3.

Comparative Example 4

1.125 g of copper acetate monohydrate and 60 g of THF were mixed, and the mixture was stirred for 3 hours to obtain a copper acetate solution. To the obtained copper acetate solution was then added 0.891 g of PLYSURF A208F which is a phosphoric acid ester compound, and the mixture was stirred for 30 minutes to obtain a solution E. 10 g of THF was added to 0.670 g of n-butylphosphonic acid (manufactured by Nippon Chemical Industrial Co., Ltd.), and the mixture was stirred for 30 minutes to obtain a solution F. The solution F was added to the solution E while the solution E was stirred, and the mixture was stirred at room temperature for 1 minute. To the resultant solution was then added 25 g of toluene, and the mixture was stirred at room temperature for 1 minute to obtain a solution G. This solution G was placed in a flask and subjected to solvent removal using a rotary evaporator under heating by means of an oil bath. The temperature of the oil bath was controlled to 105° C. A solution H according to Comparative Example 4 which had been subjected to the solvent removal was then collected from the flask. The solution H which is a dispersion of fine particles of copper butylphosphonate was transparent, and the fine particles were well dispersed therein.

To the solution H according to Comparative Example 4 was added 4.400 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a UV-IR-absorbing composition according to Comparative Example 4. An optical filter according to Comparative Example 4 was produced in the same manner as in Comparative Example 2, except that the UV-IR-absorbing composition according to Comparative Example 4 was used instead of the UV-IR-absorbing composition according to Comparative Example 2, that the thickness of the UV-IR-absorbing layer was adjusted to 1002 μm, and that the humidification treatment of the film was not performed. Transmittance spectra shown by the optical filter according to Comparative Example 4 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Moreover, based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 4 at an incident angle of 0°, transmittance spectra were calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 4 was changed to 1216 μm and 385 μm. The results of observing these transmittance spectra are shown in Tables 9 and 10 as Comparative Calculation Example 4-A and Comparative Calculation Example 4-B.

Comparative Example 5

An optical filter according to Comparative Example 5 was produced in the same manner as in Example 2, except that the thickness of the UV-IR-absorbing layer was adjusted to 191 μm and that the humidification treatment of the film was not performed. Transmittance spectra shown by the optical filter according to Comparative Example 5 were measured, and the results of observing the transmittance spectrum shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 5 at an incident angle of 0°, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 5 was changed to 148 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 5.

Comparative Examples 6 and 7

Optical filters according to Comparative Examples 6 and 7 were each produced in the same manner as in Example 2, except that the thickness of the UV-IR-absorbing layer was adjusted as shown in Table 9 and that the humidification treatment of the film was adjusted as shown in Table 6. Transmittance spectra shown by the optical filters according to Comparative Examples 6 and 7 were measured, and the results of observing the transmittance spectra shown thereby at an incident angle of 0° are shown in Tables 9 and 10. Based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 6 at an incident angle of 0°, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 6 was changed to 155 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 6. Additionally, based on the results of the measurement of the transmittance spectrum shown by the optical filter according to Comparative Example 7 at an incident angle of 0°, a transmittance spectrum was calculated on the assumption that the thickness of the UV-IR-absorbing layer of the optical filter according to Comparative Example 7 was changed to 161 μm. The results of observing this transmittance spectrum are shown in Tables 9 and 10 as Comparative Calculation Example 7.

Comparative Example 8

A solution D (dispersion of fine particles of copper phenyl-based phosphonate) according to Comparative Example 8 was prepared in the same manner as in Comparative Example 1. 0.225 g of copper acetate monohydrate and 36 g of THF were mixed, and the mixture was stirred for 3 hours to obtain a copper acetate solution. To the obtained copper acetate solution was then added 0.178 g of PLYSURF A208F (manufactured by DKS Co., Ltd.) which is a phosphoric acid ester compound, and the mixture was stirred for 30 minutes to obtain a solution E. 10 g of THF was added to 0.134 g of n-butylphosphonic acid (manufactured by Nippon Chemical Industrial Co., Ltd.), and the mixture was stirred for 30 minutes to obtain a solution F. The solution F was added to the solution E while the solution E was stirred, and the mixture was stirred at room temperature for 1 minute. To the resultant solution was then added 25 g of toluene, and the mixture was stirred at room temperature for 1 minute to obtain a solution G. This solution G was placed in a flask and subjected to solvent removal using a rotary evaporator under heating by means of an oil bath. The temperature of the oil bath was controlled to 105° C. A solution H according to Comparative Example 8 which had been subjected to the solvent removal was then collected from the flask. To the solution D according to Comparative Example 8 was added 2.200 g of a silicone resin (manufactured by Shin-Etsu Chemical Co., Ltd., product name: KR-300), and the mixture was stirred for 30 minutes to obtain a solution I according to Comparative Example 8. The solution H according to Comparative Example 8 was added to the solution I according to Comparative Example 8, and the mixture was stirred. Aggregation of copper phosphonate particles occurred and a UV-IR-absorbing composition having a high transparency could not be obtained.

Comparative Example 9

An attempt to prepare a UV-IR-absorbing composition containing n-butylphosphonic acid, as the only phosphonic acid, in an amount shown in Table 4 and no alkoxysilane monomer resulted in aggregation of copper phosphonate particles, and a homogeneous UV-IR-absorbing composition having a high transparency could not be obtained.

According to Table 7, the optical filters according to Examples 1 to 38 have the optical characteristics (i) to (vii). Moreover, according to Tables 11, 13, 15, 17, and 19, the optical filters according to Examples 1, 2, and 16 to 18 further have the optical characteristics (viii) to (xi). Furthermore, according to other results (incident angles: 0° to 65°) (not shown) of the transmittance spectrum measurement of the optical filters according to Examples 3 to 15 and 19 to 38, the optical filters according to these Examples also further have the optical characteristics (viii) to (xi).

According to Table 9, the optical filter according to Comparative Example 1 does not have the optical characteristics (ii), (vi), and (vii), and does not have the desired properties in the infrared region. Additionally, Comparative Calculation Example 1 indicates that an increase in thickness of the UV-IR-absorbing layer can improve the infrared region properties but shortens the first IR cut-off wavelength, resulting in failure to achieve the optical characteristic (iv). These indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced with the use of the UV-IR-absorbing composition according to Comparative Example 1. Likewise, the results for Comparative Example 2 and Comparative Calculation Example 2 and the results for Comparative Example 3 and Comparative Calculation Example 3 in Table 9 indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced with the use of the UV-IR-absorbing compositions according to Comparative Examples 2 and 3.

According to Table 9, the optical filter according to Comparative Example 4 does not have the optical characteristics (iii) and (v), and does not have the desired properties in the ultraviolet region. Additionally, Comparative Calculation Example 4-A indicates that an increase in thickness of the UV-IR-absorbing layer can achieve the optical characteristics (iii) and (v) but makes it difficult to achieve the optical characteristic (i). Comparative Calculation Example 4-B indicates that a decrease in thickness of the UV-IR-absorbing layer can improve the optical characteristic (i) but much worsens the optical characteristics (iii) and (v), and also increases the maximum transmittance in the wavelength range of 750 to 1080 nm. These indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced with the use of the UV-IR-absorbing composition according to Comparative Example 4.

According to Table 9, the optical filter according to Comparative Example 5 does not have the optical characteristics (i) and (iv). Comparative Calculation Example 5 indicates that a decrease in thickness of the UV-IR-absorbing layer increases the average transmittance in the wavelength range of 450 to 600 nm but does not change the IR cut-off wavelength very much, and also increases the maximum transmittance in the wavelength range of 750 to 1080 nm. These indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced by the method for producing the optical filter according to Comparative Example 5. It is indicated that the humidification treatment not only promotes the hydrolysis and polycondensation of the alkoxysilane monomers in the UV-IR-absorbing composition to promote the curing of the UV-IR-absorbing layer, but also affects a transmittance spectrum of the optical filter.

According to Table 9, the optical filter according to Comparative Example 6 does not have the optical characteristic (iv). Comparative Calculation Example 6 indicates that a decrease in thickness of the UV-IR-absorbing layer can increase the IR cut-off wavelength but also increases the maximum transmittance in the wavelength range of 750 to 1080 nm. These indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced by the method for producing the optical filter according to Comparative Example 6. In particular, it is indicated that the humidification treatment conditions in Comparative Example 6 are insufficient.

According to Table 9, the optical filter according to Comparative Example 7 does not have the optical characteristics (i) and (iv). Comparative Calculation Example 7 indicates that a decrease in thickness of the UV-IR-absorbing layer can increase the IR cut-off wavelength but also increases the maximum transmittance in the wavelength range of 750 to 1080 nm. These indicate that an optical filter having all the optical characteristics (i) to (v) cannot be produced by the method for producing the optical filter according to Comparative Example 7. In particular, it is indicated that the humidification treatment conditions in Comparative Example 7 are insufficient.

As shown in Table 2, the UV-IR-absorbing composition according to Example 3 has the highest percentage content of n-butylphosphonic acid and the UV-IR-absorbing composition according to Example 5 has the lowest percentage content of n-butylphosphonic acid among the UV-IR-absorbing compositions according to Examples 3 to 5. This fact and Table 8 indicate that an increase in the percentage content of the alkyl-based phosphonic acid in the UV-IR-absorbing composition expands the wavelength range where the spectral transmittance is 1% or less within the wavelength range of 700 to 1200 nm to the long-wavelength side and expands the wavelength range where the spectral transmittance is 0.1% or less within the wavelength range of 700 to 1200 nm to the long-wavelength side. The same can be said for Examples 6 to 8, for Examples 9 and 10, and for Examples 11 to 15.

As shown in Table 2, the UV-IR-absorbing composition according to Example 11 has the highest percentage content of n-butylphosphonic acid, the UV-IR-absorbing composition according to Example 12 has the second highest percentage content of n-butylphosphonic acid, the UV-IR-absorbing composition according to Example 13 has the third highest percentage content of n-butylphosphonic acid, and the UV-IR-absorbing composition according to Example has the lowest percentage content of n-butylphosphonic acid among the UV-IR-absorbing compositions according to Examples 11 to 15. According to the results for Examples 11 to 15 in Table 7, Example 11 is the lowest, Example 12 is the second lowest, Example 13 is the third lowest, and Example 15 is the highest in terms of the maximum transmittance of the optical filter in the wavelength range of 1000 to 1100 nm and the maximum transmittance of the optical filter in the wavelength range of 1100 to 1200 nm. These indicate that the performance of shielding against light with a wavelength in the infrared region is improved by increasing the percentage content of the alkyl-based phosphonic acid in the UV-IR-absorbing composition within the given range.

As shown in Table 2, the UV-IR-absorbing composition according to Example 7 has the highest percentage content of 4-bromophenylphosphonic acid and the UV-IR-absorbing composition according to Example 13 has the lowest percentage content of 4-bromophenylphosphonic acid among the UV-IR-absorbing compositions according to Examples 7, 10, and 13. According to the results for Examples 7, 10, and 13 in Table 7, the higher percentage content of 4-bromophenylphosphonic acid the UV-IR-absorbing composition has, the greater the UV cut-off wavelength is. This indicates that the optical characteristics of the optical filter can be optimized by adjusting the percentage content of 4-bromophenylphosphonic acid in the UV-IR-absorbing composition.

The UV-IR-absorbing compositions using which the optical filters according to Examples 22 to 37 and Comparative Examples 5 to 7 were produced were prepared in the same manner as for the UV-IR-absorbing composition according to Example 2. However, as shown in Tables 7 to 10, the optical filters according to these Examples and these Comparative Examples have different optical characteristics from those of the optical filter according to Example 2. As described above, the humidification treatment was performed in order to promote the hydrolysis and polycondensation of the alkoxysilanes contained in the UV-IR-absorbing compositions. Depending on the conditions of the humidification treatment, the average transmittance in the wavelength range of 450 to 600 nm and the IR cut-off wavelength differed among the optical filters according to these Examples and these Comparative Examples.

According to the results for Comparative Calculation Examples 5 to 7 in Table 9, the UV cut-off wavelength can be adjusted by changing the thickness of the UV-IR-absorbing layer. However, when any of the methods for producing the optical filters according to Comparative Examples 5 to 7 are employed, it is difficult to keep an IR cut-off wavelength within the desired range and satisfy the optical characteristics (i) to (xi) exclusive of the optical characteristics related to the IR cut-off wavelength as well. Thus, the amount of water vapor (water vapor exposure amount) in an environment to which the treated article had been exposed in the humidification treatment in each of Examples or each of some Comparative Examples was determined as follows. The results are shown in Tables 3 and 6. A saturated water vapor pressure e [hPa] at a temperature t [° C.] was determined by Tetens' equation: e=6.11×10^((7.5t/(t+237.3))). A water vapor concentration ρv [g/m³] was determined using the saturated water vapor pressure e [hPa] and a relative humidity φ[%] by the following equation: ρv=217×e×φ/(t+273.15). “Amount of water vapor×hour [mol/m³·hour]” was defined as the water vapor exposure amount. As shown in Tables 3 and 6, it is indicated that when the temperature is or more, the humidification treatment performed at a relative humidity of 70% or more for a treatment time of 1 hour or more results in achievement of good optical characteristics. These treatment conditions correspond to the conditions for achieving a water vapor exposure amount of 5.0 [mol/m³·hour] or more. It is indicated that extending the treatment time to ensure a similar water vapor exposure amount results in achievement of good optical characteristics when the temperature is as low as 40° C. and the relative humidity is 70% in the humidification treatment or when the temperature is 60° C. and the relative humidity is as low as 40% in the humidification treatment. These results indicate that the humidification treatment is desirably performed for a short period of time in an environment at a temperature of 60° C. or more and a relative humidity of 70% or more to efficiently provide good optical characteristics for the optical filter.

TABLE 1 Material used and amount [g] thereof Solution H (composition containing copper alkyl-based phosphonate Thick- Alkyl- ness Solution D (composition containing copper phenyl-based phosphonate) based [μm] Phenyl-based phosphonic acid phosphonic of Phenyl- 4-bromo- 4-fluoro- Copper acid Copper UV- phos- phenyl- phenyl- Phosphoric Alkoxysilane acetate n-butyl- Phosphoric acetate Matrix IR- phonic phosphonic phosphonic acid ester monomer mono- phosphonic acid ester mono- (silicone absorb- acid acid acid A208N A208F MTES TEOS hydrate acid A208N A208F hydrate resin) ing [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] layer Ex. 1 0.441 0.661 — 0.412 — 1.934 0.634 1.125 0.144 0.129 — 0.225 2.200 170 Ex. 2 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 135 Ex. 3 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.433 0.386 — 0.675 1.257 178 Ex. 4 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 1.257 154 Ex. 5 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.144 0.129 — 0.225 1.257 143 Ex. 6 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.433 0.386 — 0.675 2.200 212 Ex. 7 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 182 Ex. 8 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.144 0.129 — 0.225 2.200 162 Ex. 9 0.265 0.925 — 0.412 — 2.166 0.710 1.125 0.433 0.386 — 0.675 2.200 193 Ex. 10 0.265 0.925 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 152 Ex. 11 0.441 0.661 — 0.412 — 2.166 0.710 1.125 0.433 0.386 — 0.675 2.200 180 Ex. 12 0.441 0.661 — 0.412 — 2.166 0.710 1.125 0.361 0.322 — 0.563 2.200 171 Ex. 13 0.441 0.661 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 158 Ex. 14 0.441 0.661 — 0.412 — 2.166 0.710 1.125 0.216 0.193 — 0.338 2.200 152 Ex. 15 0.441 0.661 — 0.412 — 2.166 0.710 1.125 0.144 0.129 — 0.225 2.200 140 Ex. 16 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 132 Ex. 17 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 193 Ex. 18 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.433 0.386 — 0.675 2.200 183 Ex. 19 0.176 1.058 — — 0.412 2.166 0.710 1.125 0.433 — 0.386 0.675 2.200 198 Ex. 20 0.441 — 0.476 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 168 Ex. 21 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200  76 Ex. 38 0.176 1.058 — 0.412 — 2.166 0.710 1.125 0.289 0.257 — 0.450 2.200 168

TABLE 2 Amount- Amount- Solution H of- of- Solution D (composition containing (composition containing substance substance copper phenyl-based phosphonate) copper alkyl-based ratio of ratio of Phenyl-based phosphonate halo- phenyl- phosphonic acid Alkyl- genated based Halo- based phenyl- phos- Percentage content (mol %) gen- phosphonic phosphonic phonic of each phosphonic acid with Phenyl- ated Copper acid Copper acid to acid to respect to total phosphonic acids phos- phos- Alkoxysilane acetate n-butyl- acetate phenyl- alkyl-based Phenyl- 4-bromo- phonic phonic monomer mono- phosphonic mono- phos- phos- phos- phenyl n-butyl acid acid MTES TEOS hydrate acid hydrate phonic phonic phonic phosphonic phosphonic [mol] [mol] [mol] [mol] [mol] [mol] [mol] acid acid acid acid acid Ex. 1 0.00279 0.00279 0.0108 0.00304 0.00563 0.00104 0.00113 1.0 5.4 42.1 42.1 15.7 Ex. 2 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 3 0.00112 0.00446 0.0121 0.00341 0.00563 0.00313 0.00338 4.0 1.8 12.9 51.2 35.9 Ex. 4 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 5 0.00112 0.00446 0.0121 0.00341 0.00563 0.00104 0.00113 4.0 5.4 16.9 67.4 15.7 Ex. 6 0.00112 0.00446 0.0121 0.00341 0.00563 0.00313 0.00338 4.0 1.8 12.9 51.2 35.9 Ex. 7 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 8 0.00112 0.00446 0.0121 0.00341 0.00563 0.00104 0.00113 4.0 5.4 16.9 67.4 15.7 Ex. 9 0.00167 0.00390 0.0121 0.00341 0.00563 0.00313 0.00338 2.3 1.8 19.2 44.8 36.0 Ex. 10 0.00167 0.00390 0.0121 0.00341 0.00563 0.00209 0.00225 2.3 2.7 21.8 50.9 27.3 Ex. 11 0.00279 0.00279 0.0121 0.00341 0.00563 0.00313 0.00338 1.0 1.8 32.0 32.0 35.9 Ex. 12 0.00279 0.00279 0.0121 0.00341 0.00563 0.00261 0.00282 1.0 2.1 34.1 34.1 31.9 Ex. 13 0.00279 0.00279 0.0121 0.00341 0.00563 0.00209 0.00225 1.0 2.7 36.4 36.4 27.2 Ex. 14 0.00279 0.00279 0.0121 0.00341 0.00563 0.00157 0.00169 1.0 3.6 39.0 39.0 22.0 Ex. 15 0.00279 0.00279 0.0121 0.00341 0.00563 0.00104 0.00113 1.0 5.4 42.1 42.1 15.7 Ex. 16 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 17 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 18 0.00112 0.00446 0.0121 0.00341 0.00563 0.00313 0.00338 4.0 1.8 12.9 51.2 35.9 Ex. 19 0.00112 0.00446 0.0121 0.00341 0.00563 0.00313 0.00338 4.0 1.8 12.9 51.2 35.9 Ex. 20 0.00279 0.00271 0.0121 0.00341 0.00563 0.00209 0.00225 1.0 2.6 36.8 35.7 27.5 Ex. 21 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Ex. 38 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2

TABLE 3 Conditions of Water vapor Thickness [μm] of heat treatment Conditions of exposure amount UV-IR-absorbing for curing film humidification treatment [mol/m³ · hour] layer Examples 1 to 21 85° C.: 6 hours 85° C. 85% RH: 20 hours 332.3 See Table 1 Example 22 85° C.: 6 hours 85° C. 85% RH: 1 hour 16.6 179 Example 23 85° C.: 6 hours 85° C. 85% RH: 2 hours 33.2 177 Example 24 85° C.: 6 hours 85° C. 85% RH: 60 hours 997.2 170 Example 25 85° C.: 6 hours 60° C. 90% RH: 1 hour 6.5 170 Example 26 85° C.: 6 hours 60° C. 90% RH: 2 hours 13.0 175 Example 27 85° C.: 6 hours 60° C. 90% RH: 20 hours 129.8 174 Example 28 85° C.: 6 hours 60° C. 90% RH: 60 hours 389.4 168 Example 29 85° C.: 6 hours 60° C. 70% RH: 1 hour 5.1 175 Example 30 85° C.: 6 hours 60° C. 70% RH: 2 hours 10.1 178 Example 31 85° C.: 6 hours 60° C. 70% RH: 20 hours 101.0 160 Example 32 85° C.: 6 hours 60° C. 70%: 60 hours 303.0 164 Example 33 85° C.: 6 hours 60° C. 40%: 7 hours 20.2 215 Example 34 85° C.: 6 hours 40° C. 70% RH: 14 hours 27.9 190 Example 35 85° C.: 6 hours 60° C. 40% RH: 3 hours 8.7 154 Example 36 85° C.: 6 hours 60° C. 40% RH: 5 hours 14.5 152 Example 37 85° C.: 6 hours 40° C. 70% RH: 4 hours 8.0 153 Example 38 85° C.: 6 hours 85° C. 85% RH: 20 hours 332.3 168

TABLE 4 Material used and amount [g] thereof Solution H (composition containing Solution D copper alkyl-based phosphonate Thick- (composition containing copper phenyl-based phosphonate) Alkyl- ness Phenyl-based based [μm] phosphonic acid phosphonic of Phenyl- 4-bromo- Copper acid Copper UV- phos- phenyl- Phosphoric Alkoxysilane acetate n-butyl- Phosphoric acetate Matrix IR- phonic phosphonic acid ester monomer mono- phosphonic acid ester mono- (silicone absorb- acid acid A208N A208F MTES TEOS hydrate acid A208N A208F hydrate resin) ing [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] [g] layer Comparative 0.441 0.661 0.412 0     2.166 0.710 1.125 0     0     0     0     2.200 126 Example 1 Comparative 0.582 0.374 0.624 0     2.321 0.761 1.125 0     0     0     0     4.400 217 Example 2 Comparative 0.832 0     0     0.624 1.274 1.012 1.125 0     0     0     0     4.400 198 Example 3 Comparative 0     0     0     0     0     0     0     0.670 0     0.891 1.125 4.400 1002 Example 4 Comparative 0.176 1.058 0.412 0     2.166 0.710 1.125 0.289 0.257 0     0.450 2.200 191 Example 5 Comparative 0.176 1.058 0.412 0     2.166 0.710 1.125 0.289 0.257 0     0.450 2.200 217 Example 6 Comparative 0.176 1.058 0.412 0     2.166 0.710 1.125 0.289 0.257 0     0.450 2.200 218 Example 7 Comparative 0.441 0.661 0.412 0     2.166 0.710 1.125 0.134 0     0.178 0.225 2.200 — Example 8 Comparative 0     0     0     0     0     0     0     0.722 0.643 0     1.125 2.200 — Example 9

TABLE 5 Amount- Amount- Solution H of- of-sub- (composition substance stance containing ratio of ratio of Solution D (composition containing copper alkyl-based halo- phenyl- Content ratio copper phenyl-based phosphonate) phosphonate) genated based (mol) between Phenyl-based Alkyl- phenyl- phos- phosphonic acids phosphonic acid based phos- phonic in total 4-bromo- phosphonic phonic acid to phosphonic acids Phenyl- phenyl- Copper acid Copper acid to alkyl- 4-bromo- n- phos- phos- Alkoxysilane acetate n-butyl- acetate phenyl- based phenyl- Phenyl- butyl- phonic phonic monomer mono- phosphonic mono- phos- phos- phos- phos- phos- acid acid MTES TEOS hydrate acid hydrate phonic phonic phonic phonic phonic [mol] [mol] [mol] [mol] [mol] [mol] [mol] acid acid acid acid acid Comparative 0.00279 0.00279 0.0121 0.00341 0.00563 0      0      1.0 — 50.0 50.0 0.0 Example 1 Comparative 0.00368 0.00158 0.0130 0.00365 0.00563 0      0      0.4 — 70.0 30.0 0.0 Example 2 Comparative 0.00526 0       0.00715 0.00486 0.00563 0      0      0.0 — 100.0 0.0 0.0 Example 3 Comparative 0      0      0     0      0      0.00485 0.00563 — 0.0 0.0 0.0 100.0 Example 4 Comparative 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Example 5 Comparative 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Example 6 Comparative 0.00112 0.00446 0.0121 0.00341 0.00563 0.00209 0.00225 4.0 2.7 14.6 58.1 27.2 Example 7 Comparative 0.00279 0.00279 0.0121 0.00341 0.00563  0.000970 0.00113 1.0 5.8 42.6 42.6 14.8 Example 8 Comparative 0      0      0      0      0      0.00522 0.00563 0.0 0.0 0.0 100.0 Example 9

TABLE 6 Conditions of Water vapor heat treatment Conditions of exposure amount for curing film humidification treatment [mol/m³ · hour] Comparative 85° C.: 6 hours 85° C. 85% RH: 20 hours 332.3 Example 1 Comparative 85° C.: 3 hours, 85° C. 85% RH: 4 hours 66.5 Example 2 125° C.: 3 hours, 150° C.: 1 hour, 170° C.: 3 hours Comparative 85° C.: 3 hours, 85° C.85% RH: 20 hours 332.3 Example 3 125° C.: 3 hours, 150° C.: 1 hour, 170° C.: 3 hours Comparative 85° C.: 3 hours, — — Example 4 125° C.: 3 hours, 150° C.: 1 hour, 170° C.: 3 hours Comparative 85° C.: 6 hours — — Example 5 Comparative 85° C.: 6 hours 60° C. 40% RH: 1 hour 2.9 Example 6 Comparative 85° C.: 6 hours 40° C. 70% RH: 1 hour 2.0 Example 7

TABLE 7 Visible region properties Infrared region properties Ultraviolet region (i) (ii) (vi) (vii) properties Average Maximum Maximum Maximum (iii) (iii) Cut-off wavelength Thick- trans- trans- trans- trans- Maximum Maximum properties ness mittance mittance mittance mittance transmittance transmittance (iv) (v) [μm] of [%] in [%] in [%] in [%] in [%] in [%] in IR UV UV- wavelength wavelength wavelength wavelength wavelength wavelength cut-off cut-off IR- Require- range of range of range of range of range of range of wave- wave- ab- ment 450 to 750 to 1000 to 1100 to 300 to 350 300 to 360 length length sorbing Example 600 nm 1080 nm 1100 nm 1200 nm nm nm [nm] [nm] layer Ex. 1 85.48 0.99 1.60 12.11  0.00 0.02 629 391 170 Ex. 2 85.67 0.44 0.72 5.82 0.03 0.03 639 407 135 Ex. 3 80.82 0.05 0.01 0.50 0.00 0.00 634 413 178 Ex. 4 82.83 0.08 0.13 2.41 0.00 0.00 634 412 154 Ex. 5 83.41 0.72 1.21 10.61  0.00 0.00 633 412 143 Ex. 6 81.68 0.05 0.01 0.44 0.00 0.00 634 413 212 Ex. 7 82.92 0.08 0.13 2.28 0.00 0.00 633 411 182 Ex. 8 82.46 0.77 1.29 11.04  0.00 0.00 633 413 162 Ex. 9 81.00 0.05 0.01 0.38 0.00 0.00 634 407 193 Ex. 10 82.52 0.09 0.15 2.40 0.00 0.00 633 406 152 Ex. 11 83.49 0.07 0.04 0.87 0.00 0.00 630 398 180 Ex. 12 83.00 0.08 0.12 1.94 0.00 0.00 630 399 171 Ex. 13 83.01 0.22 0.37 4.42 0.00 0.00 629 398 158 Ex. 14 82.62 0.36 0.61 6.50 0.00 0.00 631 400 152 Ex. 15 84.14 0.81 1.36 11.52  0.00 0.00 632 399 140 Ex. 16 83.99 0.43 0.71 5.70 0.03 0.03 638 408 132 Ex. 17 84.75 0.06 0.08 1.96 0.00 0.00 632 408 193 Ex. 18 85.36 0.04 0.01 0.34 0.00 0.00 634 407 183 Ex. 19 82.40 0.07 0.04 0.96 0.00 0.00 632 409 198 Ex. 20 83.23 0.07 0.04 1.03 0.00 0.01 630 393 168 Ex. 21 80.60 1.00 1.37 6.84 0.02 0.14 621 400 76 Ex. 22 85.22 0.10 0.17 2.64 0.00 0.00 632 406 179 Ex. 23 85.61 0.09 0.15 2.50 0.00 0.00 633 406 177 Ex. 24 84.94 0.08 0.11 2.03 0.00 0.00 632 408 170 Ex. 25 84.51 0.16 0.26 3.27 0.00 0.00 629 403 170 Ex. 26 85.83 0.17 0.27 3.27 0.00 0.00 630 404 175 Ex. 27 85.79 0.13 0.22 2.96 0.00 0.00 631 404 174 Ex. 28 85.42 0.12 0.20 2.91 0.00 0.00 632 405 168 Ex. 29 84.19 0.21 0.33 3.62 0.00 0.00 627 403 175 Ex. 30 84.78 0.19 0.30 3.34 0.00 0.00 627 404 178 Ex. 31 85.66 0.13 0.21 3.00 0.00 0.00 630 403 160 Ex. 32 85.98 0.12 0.20 2.84 0.00 0.00 631 403 164 Ex. 33 84.11 0.11 0.07 1.10 0.00 0.00 620 406 215 Ex. 34 83.49 0.12 0.17 2.13 0.00 0.00 623 404 190 Ex. 35 84.53 0.94 0.72 4.46 0.00 0.01 628 402 154 Ex. 36 85.36 0.95 0.78 4.80 0.00 0.01 632 402 152 Ex. 37 83.77 0.91 0.69 4.25 0.00 0.02 625 400 153 Ex. 38 80.61 0.30 0.40 3.70 0.00 0.02 635 412 168

TABLE 8 Visible region properties Infrared region properties Wavelength Maximum Maximum Ultraviolet region properties range [nm] in transmittance transmittance Wavelength Wavelength Wavelength Wavelength which [%] in [%] in range [nm] in range [nm] in range [nm] in range [nm] in transmittance wavelength wavelength which which which which is 78% or range of 800 range of 800 transmittance transmittance transmittance transmittance Example more to 950 nm to 1000 nm is 1% or less is 0.1% or less is 1% or less is 0.1% or less Example 1 408 to 599 0.08 0.18 713 to 1080 753 to 965 300 to 368 300 to 363 Example 2 430 to 609 0.28 0.28 730 to 1120 778 to 910 300 to 378 300 to 369 Example 3 456 to 602 0.00 0.00 713 to 1200  743 to 1156 300 to 383 300 to 376 Example 4 440 to 603 0.00 0.01 713 to 1167  746 to 1089 300 to 383 300 to 376 Example 5 436 to 602 0.04 0.11 713 to 1092 752 to 994 300 to 384 300 to 377 Example 6 443 to 603 0.00 0.00 713 to 1200  743 to 1160 300 to 384 300 to 377 Example 7 437 to 603 0.00 0.01 713 to 1170  747 to 1091 300 to 382 300 to 376 Example 8 448 to 602 0.04 0.12 713 to 1090 752 to 990 300 to 384 300 to 377 Example 9 443 to 602 0.00 0.00 713 to 1200  743 to 1165 300 to 379 300 to 373 Example 10 435 to 602 0.01 0.02 713 to 1167  747 to 1086 300 to 379 300 to 373 Example 11 421 to 598 0.00 0.01 713 to 1200  746 to 1133 300 to 373 300 to 367 Example 12 428 to 599 0.01 0.02 713 to 1176  747 to 1094 300 to 373 300 to 368 Example 13 423 to 597 0.02 0.05 713 to 1138  750 to 1043 300 to 373 300 to 367 Example 14 429 to 600 0.02 0.06 713 to 1119  750 to 1023 300 to 374 300 to 369 Example 15 422 to 602 0.04 0.13 713 to 1087 752 to 988 300 to 375 300 to 369 Example 16 434 to 606 0.27 0.27 730 to 1120 778 to 910 300 to 378 300 to 370 Example 17 431 to 602 0.00 0.00 711 to 1177  743 to 1103 300 to 380 300 to 374 Example 18 427 to 604 0.02 0.02 712 to 1200  741 to 1172 300 to 380 300 to 373 Example 19 433 to 601 0.00 0.01 713 to 1200  745 to 1130 300 to 380 300 to 374 Example 20 419 to 599 0.00 0.00 713 to 1199  745 to 1132 300 to 369 300 to 364 Example 21 423 to 575 0.19 0.34 742 to 1080 805 to 906 300 to 368 300 to 358 Example 22 424 to 601 0.01 0.02 713 to 1163  748 to 1079 300 to 379 300 to 373 Example 23 424 to 603 0.01 0.02 713 to 1167  747 to 1085 300 to 380 300 to 374 Example 24 429 to 602 0.00 0.01 713 to 1175  746 to 1097 300 to 381 300 to 375 Example 25 421 to 598 0.01 0.03 713 to 1152  750 to 1059 300 to 377 300 to 371 Example 26 420 to 600 0.01 0.04 713 to 1151  750 to 1056 300 to 378 300 to 372 Example 27 421 to 601 0.01 0.03 713 to 1157  749 to 1067 300 to 379 300 to 373 Example 28 423 to 602 0.01 0.02 713 to 1159  748 to 1072 300 to 379 300 to 373 Example 29 422 to 595 0.02 0.05 713 to 1146  753 to 1044 300 to 377 300 to 370 Example 30 422 to 595 0.02 0.04 713 to 1149  753 to 1049 300 to 377 300 to 371 Example 31 420 to 600 0.01 0.02 713 to 1157  750 to 1069 300 to 377 300 to 371 Example 32 420 to 601 0.01 0.02 713 to 1160  749 to 1074 300 to 377 300 to 371 Example 33 425 to 587 0.01 0.01 713 to 1196  753 to 1115 300 to 379 300 to 372 Example 34 423 to 590 0.01 0.03 713 to 1170  754 to 1073 300 to 377 300 to 371 Example 35 420 to 591 0.15 0.25 749 to 1121 806 to 922 300 to 373 300 to 366 Example 36 420 to 595 0.15 0.26 749 to 1116 806 to 923 300 to 373 300 to 366 Example 37 420 to 586 0.14 0.25 748 to 1123 807 to 923 300 to 372 300 to 364 Example 38 465 to 591 0.25 0.25 725 to 1147 764 to 977 300 to 380 300 to 372

TABLE 9 Visible region properties Infrared region properties Ultraviolet region (i) (ii) (vi) (vii) properties Average Maximum Maximum Maximum (iii) (iii) Cut-off transmittance transmittance transmittance transmittance Maximum Maximum wavelength properties [%] in [%] in [%] in [%] in transmittance transmittance (iv) (v) Thickness wavelength wavelength wavelength wavelength [%] in [%] in IR cut-off UV cut-off [μm] of range of range of range of range of wavelength wavelength wave- wave- UV-IR- Requirement 450 to 750 to 1000 to 1100 to range of range of length length absorbing Example 600 nm 1080 nm 1100 nm 1200 nm 300 to 350 300 to 360 [nm] [nm] layer Comparative 86.06 7.21 11.63 48.16 0.00 0.00 632 400 126 Example 1 Comparative 82.84 1.64 3.49 33.05 0.00 0.00 619 407 200 Calculation Example 1 Comparative 86.13 7.02 11.20 46.57 0.00 0.00 632 395 217 Example 2 Comparative 82.83 1.50 3.16 30.93 0.00 0.00 619 402 347 Calculation Example 2 Comparative 84.68 7.61 12.13 49.45 0.00 0.02 631 391 198 Example 3 Comparative 81.06 2.02 4.13 35.54 0.00 0.00 619 398 303 Calculation Example 3 Comparative 79.21 0.00 0.00 0.00 1.01 13.75 646 376 1002 Example 4 Comparative 76.75 0.00 0.00 0.00 0.38 9.15 641 380 1216 Calculation Example 4-A Comparative 82.03 1.00 0.00 0.00 16.24 44.31 676 362 385 Calculation Example 4-B Comparative 76.14 0.27 0.21 1.68 0.00 0.00 600 409 191 Example 5 Comparative 79.29 1.00 0.82 4.14 0.00 0.04 601 404 148 Calculation Example 5 Comparative 79.81 0.16 0.08 1.04 0.00 0.00 605 408 217 Example 6 Comparative 83.03 1.00 0.59 3.74 0.00 0.01 618 403 155 Calculation Example 6 Comparative 77.34 0.20 0.10 1.08 0.00 0.00 600 407 218 Example 7 Comparative 80.78 1.00 0.58 3.44 0.00 0.04 609 402 161 Calculation Example 7

TABLE 10 Visible region properties Infrared region properties Wavelength Maximum Maximum Ultraviolet region properties range [nm] in transmittance transmittance Wavelength Wavelength Wavelength Wavelength which [%] in [%] in range [nm] in range [nm] in range [nm] in range [nm] in transmittance wavelength wavelength which which which which is 78% or range of 800 range of 800 transmittance transmittance transmittance transmittance Example more to 950 nm to 1000 nm is 1% or less is 0.1% or less is 1% or less is 0.1% or less Comparative 424 to 603 0.36 1.06 713 to 996 764 to 904  300 to 375 300 to 369 Example 1 Comparative 462 to 593 0.01 0.08  686 to 1067 710 to 1006 300 to 380 300 to 375 Calculation Example 1 Comparative 417 to 603 0.36 1.07 713 to 996 761 to 907  300 to 371 300 to 366 Example 2 Comparative 441 to 592 0.01 0.07  686 to 1069 709 to 1008 300 to 376 300 to 372 Calculation Example 2 Comparative 421 to 601 0.37 1.17 713 to 992 762 to 908  300 to 367 300 to 363 Example 3 Comparative 450 to 590 0.02 0.11  688 to 1061 712 to 996  300 to 372 300 to 367 Calculation Example 3 Comparative 486 to 613 0.00 0.00  712 to 1200 727 to 1200 300 to 349 300 to 345 Example 4 Comparative 508 to 606 0.00 0.00  705 to 1200 720 to 1200 300 to 352 300 to 347 Calculation Example 4-A Comparative 403 to 642 0.00 0.00  750 to 1200 772 to 1200 300 to 339 300 to 334 Calculation Example 4-B Comparative 438 to 557 0.04 0.08  714 to 1178 776 to 1024 300 to 375 300 to 368 Example 5 Comparative 430 to 564 0.25 0.40  750 to 1116 839 to 850  300 to 371 300 to 362 Calculation Example 5 Comparative 432 to 569 0.01 0.02  714 to 1198 760 to 1111 300 to 378 300 to 371 Example 6 Comparative 423 to 579 0.15 0.23  750 to 1133 811 to 937  300 to 373 300 to 365 Calculation Example 6 Comparative 435 to 561 0.02 0.03  714 to 1197 766 to 1101 300 to 375 300 to 369 Example 7 Comparative 425 to 571 0.17 0.25  750 to 1135 818 to 919  300 to 370 300 to 362 Calculation Example 7

TABLE 11 Visible region properties Infrared region properties Ultraviolet region properties (i) (ii) (vi) (vii) (iii) (iii) Average Maximum Maximum Maximum Maximum Maximum Cut-off transmittance transmittance transmittance transmittance transmittance transmittance wavelength properties [%] in [%] in [%] in [%] in [%] in [%] in (iv) (v) Require- wavelength wavelength wavelength wavelength wavelength wavelength IR cut-off UV cut-off ment range of range of range of range of range of range of wave- wave- Incident 450 to 750 to 1000 to 1100 to 300 to 300 to length length angle [°] 600 nm 1080 nm 1100 nm 1200 nm 350 nm 360 nm [nm] [nm]  0 85.48 0.99 1.60 12.11 0.00 0.02 629 391 30 83.99 0.88 1.44 11.36 0.00 0.02 627 392 35 83.35 0.83 1.37 11.04 0.00 0.01 626 392 40 82.63 0.79 1.31 10.71 0.00 0.01 626 393 45 81.75 0.75 1.26 10.30 0.00 0.01 625 393 50 80.49 0.71 1.19 9.85 0.00 0.01 623 394 55 78.06 0.67 1.12 9.31 0.00 0.01 621 395 60 73.14 0.00 1.03 8.57 0.00 0.00 618 398 65 65.87 0.56 0.93 7.67 0.00 0.00 612 402

TABLE 12 Visible region properties Infrared region properties Ultraviolet region properties Wavelength Wavelength Wavelength Wavelength Wavelength range [nm] range [nm] range [nm] range [nm] range [nm] in which in which in which in which in which Incident transmittance transmittance transmittance transmittance transmittance angle [°] is 78% or more is 1% or less is 0.1% or less is 1% or less is 0.1% or less  0 413 to 594 713 to 1080 753 to 965 300 to 368 300 to 363 30 418 to 590 710 to 1085 748 to 970 300 to 369 300 to 363 35 420 to 589 709 to 1087 746 to 980 300 to 369 300 to 364 40 421 to 586 707 to 1088 744 to 981 300 to 369 300 to 364 45 425 to 584 706 to 1091 743 to 986 300 to 370 300 to 364 50 439 to 580 705 to 1092 741 to 991 300 to 370 300 to 365 55 478 to 571 703 to 1095 738 to 991 300 to 370 300 to 365 60 — 702 to 1099 736 to 996 300 to 371 300 to 366 65 — 699 to 1102  733 to 1003 300 to 371 300 to 366

TABLE 13 Visible region properties Infrared region properties Ultraviolet region properties (i) (ii) (vi) (vii) (iii) (iii) Average Maximum Maximum Maximum Maximum Maximum Cut-off transmittance transmittance transmittance transmittance transmittance transmittance wavelength properties [%] in [%] in [%] in [%] in [%] in [%] in (iv) (v) Require- wavelength wavelength wavelength wavelength wavelength wavelength IR cut-off UV cut-off ment range of range of range of range of range of range of wave- wave- Incident 450 to 750 to 1000 to 1100 to 300 to 300 to length length angle [°] 600 nm 1080 nm 1100 nm 1200 nm 350 nm 360 nm [nm] [nm]  0 85.67 0.44 0.72 5.82 0.03 0.03 639 407 30 83.30 0.38 0.62 5.24 0.02 0.02 637 409 35 82.72 0.37 0.61 5.17 0.02 0.02 636 409 40 81.52 0.36 0.61 4.97 0.02 0.02 635 410 45 80.19 0.37 0.56 4.81 0.03 0.03 634 411 50 78.56 0.38 0.56 4.68 0.02 0.03 632 412 55 75.76 0.36 0.55 4.52 0.02 0.02 630 414 60 71.73 0.00 0.54 4.30 0.03 0.03 627 416 65 66.20 0.35 0.55 4.05 0.03 0.03 621 420

TABLE 14 Visible region properties Infrared region properties Ultraviolet region properties Wavelength Wavelength Wavelength Wavelength Wavelength range [nm] range [nm] range [nm] range [nm] range [nm] in which in which in which in which in which Incident transmittance transmittance transmittance transmittance transmittance angle [°] is 78% or more is 1% or less is 0.1% or less is 1% or less is 0.1% or less  0 438 to 603 730 to 1120 778 to 910 300 to 378 300 to 369 30 456 to 598 726 to 1123 771 to 974 300 to 379 300 to 372 35 462 to 596 725 to 1124 771 to 923 300 to 379 300 to 372 40 467 to 593 724 to 1127 768 to 950 300 to 380 300 to 373 45 472 to 589 723 to 1128 768 to 956 300 to 380 300 to 373 50 482 to 582 721 to 1129  766 to 1004 300 to 381 300 to 373 55 527 to 560 720 to 1130 765 to 971 300 to 381 300 to 374 60 — 718 to 1134 762 to 981 300 to 382 300 to 375 65 — 716 to 1134 761 to 982 300 to 382 300 to 375

TABLE 15 Visible region properties Infrared region properties Ultraviolet region properties (i) (ii) (vi) (vii) (iii) (iii) Average Maximum Maximum Maximum Maximum Maximum Cut-off transmittance transmittance transmittance transmittance transmittance transmittance wavelength properties [%] in [%] in [%] in [%] in [%] in [%] in (iv) (v) Require- wavelength wavelength wavelength wavelength wavelength wavelength IR cut-off UV cut-off ment range of range of range of range of range of range of wave- wave- Incident 450 to 750 to 1000 to 1100 to 300 to 300 to length length angle [°] 600 nm 1080 nm 1100 nm 1200 nm 350 nm 360 nm [nm] [nm]  0 83.99 0.43 0.71 5.70 0.03 0.03 638 408 30 81.67 0.38 0.61 5.14 0.02 0.02 636 409 35 81.09 0.36 0.59 5.06 0.02 0.02 635 410 40 79.92 0.35 0.60 4.88 0.02 0.02 634 411 45 78.62 0.37 0.55 4.71 0.03 0.03 633 412 50 77.02 0.37 0.55 4.59 0.02 0.03 631 413 55 74.28 0.35 0.54 4.43 0.02 0.02 629 414 60 70.32 0.00 0.53 4.21 0.03 0.03 625 417 65 64.90 0.34 0.54 3.97 0.03 0.03 619 422

TABLE 16 Visible region properties Infrared region properties Ultraviolet region properties Wavelength Wavelength Wavelength Wavelength Wavelength range [nm] range [nm] range [nm] range [nm] range [nm] in which in which in which in which in which Incident transmittance transmittance transmittance transmittance transmittance angle [°] is 78% or more is 1% or less is 0.1% or less is 1% or less is 0.1% or less  0 446 to 600 730 to 1120 778 to 910 300 to 378 300 to 370 30 466 to 594 726 to 1124 771 to 956 300 to 379 300 to 372 35 469 to 592 725 to 1125 769 to 976 300 to 379 300 to 372 40 473 to 588 723 to 1127 768 to 943 300 to 380 300 to 373 45 480 to 583 722 to 1128 767 to 961 300 to 380 300 to 373 50 499 to 573 721 to 1130  765 to 1009 300 to 381 300 to 373 55 — 719 to 1132 765 to 854 300 to 381 300 to 374 60 — 718 to 1135 761 to 852 300 to 382 300 to 375 65 — 716 to 1132 761 to 982 300 to 382 300 to 375

TABLE 17 Visible region properties Infrared region properties Ultraviolet region properties (i) (ii) (vi) (vii) (iii) (iii) Average Maximum Maximum Maximum Maximum Maximum Cut-off transmittance transmittance transmittance transmittance transmittance transmittance wavelength properties [%] in [%] in [%] in [%] in [%] in [%] in (iv) (v) Require- wavelength wavelength wavelength wavelength wavelength wavelength IR cut-off UV cut-off ment range of range of range of range of range of range of wave- wave- Incident 450 to 750 to 1000 to 1100 to 300 to 300 to length length angle [°] 600 nm 1080 nm 1100 nm 1200 nm 350 nm 360 nm [nm] [nm]  0 84.75 0.06 0.08 1.96 0.00 0.00 632 408 30 83.73 0.04 0.07 1.69 0.00 0.00 630 410 35 83.25 0.04 0.05 1.62 0.00 0.00 630 410 40 82.55 0.03 0.05 1.55 0.00 0.00 629 411 45 81.04 0.03 0.05 1.46 0.00 0.00 628 412 50 79.25 0.03 0.05 1.37 0.00 0.00 626 413 55 77.06 0.03 0.04 1.26 0.00 0.00 624 414 60 73.44 0.00 0.03 1.17 0.00 0.00 620 417 65 67.66 0.02 0.03 1.04 0.00 0.00 616 420

TABLE 18 Visible region properties Infrared region properties Ultraviolet region properties Wavelength Wavelength Wavelength Wavelength Wavelength range [nm] range [nm] range [nm] range [nm] range [nm] in which in which in which in which in which Incident transmittance transmittance transmittance transmittance transmittance angle [°] is 78% or more is 1% or less is 0.1% or less is 1% or less is 0.1% or less  0 439 to 596 711 to 1177 778 to 910 300 to 380 300 to 374 30 444 to 594 708 to 1182 739 to 1109 300 to 382 300 to 375 35 447 to 593 708 to 1183 738 to 1110 300 to 382 300 to 376 40 454 to 591 706 to 1185 737 to 1113 300 to 382 300 to 376 45 466 to 588 705 to 1187 734 to 1118 300 to 383 300 to 377 50 474 to 582 704 to 1189 733 to 1120 300 to 383 300 to 377 55 493 to 569 702 to 1191 731 to 1121 300 to 384 300 to 378 60 — 700 to 1194 728 to 1121 300 to 385 300 to 378 65 — 698 to 1199 726 to 1130 300 to 385 300 to 379

TABLE 19 Visible region properties Infrared region properties Ultraviolet region properties (i) (ii) (vi) (vii) (iii) (iii) Average Maximum Maximum Maximum Maximum Maximum Cut-off transmittance transmittance transmittance transmittance transmittance transmittance wavelength properties [%] in [%] in [%] in [%] in [%] in [%] in (iv) (v) Require- wavelength wavelength wavelength wavelength wavelength wavelength IR cut-off UV cut-off ment range of range of range of range of range of range of wave- wave- Incident 450 to 750 to 1000 to 1100 to 300 to 300 to length length angle [°] 600 nm 1080 nm 1100 nm 1200 nm 350 nm 360 nm [nm] [nm]  0 85.36 0.04 0.01 0.34 0.00 0.00 634 407 30 83.91 0.03 0.02 0.28 0.00 0.00 631 409 35 83.28 0.03 0.01 0.27 0.00 0.00 631 409 40 82.56 0.03 0.01 0.25 0.00 0.00 630 410 45 81.51 0.03 0.01 0.24 0.00 0.00 629 411 50 79.71 0.03 0.01 0.21 0.00 0.00 627 411 55 77.53 0.03 0.01 0.21 0.00 0.00 625 412 60 74.21 0.00 0.01 0.19 0.00 0.00 621 415 65 69.45 0.01 0.01 0.16 0.00 0.00 616 419

TABLE 20 Visible region properties Infrared region properties Ultraviolet region properties Wavelength Wavelength Wavelength Wavelength Wavelength range [nm] range [nm] range [nm] range [nm] range [nm] in which in which in which in which in which Incident transmittance transmittance transmittance transmittance transmittance angle [°] is 78% or more is 1% or less is 0.1% or less is 1% or less is 0.1% or less  0 434 to 598 712 to 1200 778 to 910 300 to 380 300 to 373 30 440 to 595 709 to 1200 737 to 1174 300 to 381 300 to 375 35 443 to 593 708 to 1200 736 to 1175 300 to 381 300 to 375 40 447 to 591 707 to 1200 735 to 1176 300 to 382 300 to 375 45 458 to 589 706 to 1200 733 to 1179 300 to 382 300 to 376 50 472 to 584 705 to 1200 732 to 1179 300 to 382 300 to 376 55 488 to 572 703 to 1200 730 to 1182 300 to 383 300 to 377 60 — 701 to 1200 728 to 1184 300 to 384 300 to 378 65 — 699 to 1200 726 to 1186 300 to 384 300 to 378 

The invention claimed is:
 1. A method for manufacturing an optical filter, the optical filter comprising a UV-IR-absorbing layer, the method comprising: preparing a UV-IR-absorbing composition, the UV-IR-absorbing composition including a UV-IR absorber containing a phosphonic acid and a copper component, and a curable resin dispersing the UV-IR absorber therein; forming a UV-IR-absorbing composition film by applying the UV-IR-absorbing composition; and curing the UV-IR-absorbing composition film into the UV-IR-absorbing layer, wherein curing the UV-IR-absorbing composition film includes: exposing the UV-IR-absorbing composition film to an environment at temperature of 50 degree Celsius to 200 degree Celsius; and exposing the UV-IR-absorbing composition film to an environment at temperature of 40 degree Celsius to 100 degree Celsius and at relative humidity of 40% to 100%, and wherein the optical filter, in spectral transmittance at incident angle of 0 degree, has an average transmittance of 78% or more in the wavelength range of 450 nm to 600 nm, a maximum transmittance of 1% or less in the wavelength range of 750 nm to 1080 nm, a decreasing spectral transmittance with increasing wavelength in the wavelength range of 600 nm to 750 nm, and a first IR cut-off wavelength corresponding to transmittance of 50% in the wavelength range of 620 nm to 680 nm.
 2. The method for manufacturing an optical filter according to claim 1, wherein the optical filter, in spectral transmittance at incident angle of 0 degree, has a maximum transmittance of 1% or less in the wavelength range of 300 nm to 350 nm.
 3. The method for manufacturing an optical filter according to claim 1, wherein the optical filter, in spectral transmittance at incident angle of 0 degree, has an increasing spectral transmittance with increasing wavelength in the wavelength range of 350 nm to 450 nm, and a first UV cut-off wavelength corresponding to transmittance of 50% in the wavelength range of 380 nm to 430 nm.
 4. The method for manufacturing an optical filter according to claim 1, wherein the optical filter, in spectral transmittance at incident angle of 0 degree, has a maximum transmittance of 3% or less in the wavelength range of 1000 nm to 1100 nm.
 5. The method for manufacturing an optical filter according to claim 1, wherein the optical filter, in spectral transmittance at incident angle of 0 degree, has a maximum transmittance of 15% or less in the wavelength range of 1100 nm to 1200 nm.
 6. The method for manufacturing an optical filter according to claim 1, wherein the phosphonic acid includes a phosphonic acid with alkyl group.
 7. The method for manufacturing an optical filter according to claim 1, wherein the phosphonic acid includes a first phosphonic acid with phenyl group and a second phosphonic acid with alkyl group, wherein the first phosphonic acid includes at least one or more selected from the group consisting of a phosphonic acid with unsubstituted phenyl group and a phosphonic acid with phenyl group in which at least one hydrogen atom is substituted with a halogen atom.
 8. The method for manufacturing an optical filter according to claim 1, wherein the phosphonic acid includes a first phosphonic acid with phenyl group and a second phosphonic acid with alkyl group, and wherein the first phosphonic acid includes a phosphonic acid with unsubstituted phenyl group and a phosphonic acid with phenyl group in which at least one hydrogen atom is substituted with a halogen atom. 